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Merck
CN

494070

6,6′′-二溴-2,2′:6′,2′-三吡啶

90%

别名:

6,6′′-二溴-2,2′:6′,2′′-三吡啶

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关于此项目

经验公式(希尔记法):
C15H9Br2N3
化学文摘社编号:
分子量:
391.06
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
90%
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产品名称

6,6′′-二溴-2,2′:6′,2′-三吡啶, 90%

InChI

1S/C15H9Br2N3/c16-14-8-2-6-12(19-14)10-4-1-5-11(18-10)13-7-3-9-15(17)20-13/h1-9H

SMILES string

Brc1cccc(n1)-c2cccc(n2)-c3cccc(Br)n3

InChI key

PYMBATDYUCQLBC-UHFFFAOYSA-N

assay

90%

mp

257-263 °C (lit.)

functional group

bromo

Quality Level

Application

6,6′′-二溴-2,2′:6′,2′′-三联吡啶可用于合成新的双取代三联吡啶配体。

General description

6,6′′-二溴-2,2′:6′,2′′-三联吡啶是取代的三联吡啶,可以由2,6-二溴吡啶合成。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

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A Novel One-Pot Synthesis of 6,6''-Dibromo-2,2':6'2''-terpyridine.
Uchida Y, et al.
ChemInform, 26(50) (1995)
Kogularamanan Suntharalingam et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(47), 15133-15141 (2012-10-13)
A new disubstituted terpyridine ligand and the corresponding tri-copper(II) complex have been prepared and characterised. The binding affinity and binding mode of this tri-copper complex (as well as the previously reported mono- and di-copper analogues) towards duplex DNA were determined
Lingjing Chen et al.
Dalton transactions (Cambridge, England : 2003), 48(26), 9596-9602 (2019-02-20)
A new pentadentate quinoline-pyridine ligand and its iron (1), cobalt (2) and nickel (3) complexes have been synthesized and characterized. The iron complex exhibits excellent photocatalytic activity towards CO2-to-CO conversion with a TON(CO) of 544 and a selectivity of 99.3%

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