Quality Segment
assay
95%
refractive index
n20/D 1.668 (lit.)
bp
269 °C/752.5 mmHg (lit.)
density
1.629 g/mL at 25 °C (lit.)
functional group
bromo
SMILES string
Brc1csc2ccccc12
InChI
1S/C8H5BrS/c9-7-5-10-8-4-2-1-3-6(7)8/h1-5H
InChI key
SRWDQSRTOOMPMO-UHFFFAOYSA-N
General description
3-Bromothianaphthene is a heteroaryl halide. It undergoes Suzuki-Miyaura reaction with phenylboronic acid (PBA) or 3-thienylboronic acid in the presence of a novel heterogeneous Pd catalyst [Pd@PDEB, PDEB=poly(1,3-diethynylbenzene)]. The substitution reaction of 3-bromothianaphthene with piperidine to form 3-piperidinothianaphthene as the major product has been reported.
Application
3-Bromothianaphthene may be used in the synthesis of (benzo[b]thiophen-3-yl)trimethylstannane.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)