49661
4-戊烯酸甲酯
≥95.0% (GC)
别名:
4-Pentenoic acid methyl ester, Allylacetic acid methyl ester, 烯丙基乙酸甲酯
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关于此项目
经验公式（希尔记法）:
C6H10O2
化学文摘社编号:
分子量:
114.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
≥95.0% (GC)
InChI
1S/C6H10O2/c1-3-4-5-6(7)8-2/h3H,1,4-5H2,2H3
SMILES string
COC(=O)CCC=C
InChI key
SHCSFZHSNSGTOP-UHFFFAOYSA-N
assay
≥95.0% (GC)
Quality Level
functional group
allyl, ester
General description
4-戊烯酸甲酯是由1-戊烯酸与甲醇酯化而制得的不饱和甲酯。它通过丙酮引发的光化学反应与甲酰胺进行酰胺化，形成1：1加合物。已经报告了4-戊烯酸甲酯与不同的Mo（VI）亚烷基复合物的复分解反应。它在使用RuII（H20）6（tos）2（tos =对甲苯磺酸盐）作为催化剂的 exo，exo-5，6-双（甲氧基甲基）-7-氧杂双环[2.2.1]庚-2-烯聚合过程中充当链转移剂。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
84.2 °F - closed cup
flash_point_c
29 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
The Light-Induced Amidation of Terminal Olefins1.
Elad D and Rokach J.
The Journal of Organic Chemistry, 29(7), 1855-1859 (1964)
Coupling of terminal olefins by molybdenum (VI) imido alkylidene complexes.
Fox HH, et al.
Organometallics, 13(2), 635-639 (1994)
Chain transfer during the aqueous ring-opening metathesis polymerization of 7-oxanorbornene derivatives.
France MB, et al.
Macromolecules, 26(18), 4742-4747 (1993)
Majd Al-Naji et al.
ChemSusChem, 12(12), 2628-2636 (2019-04-18)
The need for more sustainable products and processes has led to the use of new methodologies with low carbon footprints. In this work, an efficient tandem process is demonstrated for the liquid-phase catalytic upgrading of lignocellulosic biomass-derived γ-valerolactone (GVL) with
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