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496839

3-丁烯-1-醇

Name: 3-丁烯-1-醇
Brand: ALDRICH

96%

别名:

烯丙基甲醇

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关于此项目

线性分子式:

CH₂=CHCH₂CH₂OH

化学文摘社编号:

627-27-0

分子量:

72.11

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24873086

EC Number:

210-991-3

Beilstein/REAXYS Number:

1633504

MDL number:

MFCD00002959

Assay:

96%

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属性

Quality Level

100

assay

96%

refractive index

n20/D 1.421 (lit.)

bp

112-114 °C (lit.)

density

0.838 g/mL at 25 °C (lit.)

functional group

allyl, hydroxyl

SMILES string

OCCC=C

InChI

1S/C4H8O/c1-2-3-4-5/h2,5H,1,3-4H2

InChI key

ZSPTYLOMNJNZNG-UHFFFAOYSA-N

说明

General description

3-丁烯-1-醇是一种高烯丙醇，可以通过使用铈催化剂脱水1,4-丁二醇来制备。用红外光谱和¹H NMR光谱数据研究了3-丁烯-1-醇的分子内氢键。对其微波光谱进行了记录和分析。研究了钛-有机铝体系3-丁烯-1-醇的烷基化反应。据报告，其气相生成焓为-147.3 ± 1.8kJ mol^-1。

Application

用于研究锰催化的烯烃氢肼化。也用于研究炔丙基乙酸酯转化为氯化铁催化的醚。

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pictograms

GHS02,GHS07

signalword

Warning

hcodes

H226,H315,H319,H335

pcodes

P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

91.4 °F - closed cup

flash_point_c

33 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Hydrazines and azides via the metal-catalyzed hydrohydrazination and hydroazidation of olefins.

Jérôme Waser et al.

Journal of the American Chemical Society, 128(35), 11693-11712 (2006-08-31)

The discovery, study, and implementation of the Co- and Mn-catalyzed hydrohydrazination and hydroazidation reactions of olefins are reported. These reactions are equivalent to direct hydroaminations of C-C double bonds with protected hydrazines or hydrazoic acid but are based on a

Transition metal promoted alkylations of unsaturated alcohols: the methylation and ethylation of 3-buten-1-ol using titanium tetrachloride-organoaluminum systems.

Youngblood AV, et al.

Journal of Organometallic Chemistry, 146(3), 221-228 (1978)

Microwave spectrum, intramolecular hydrogen bond, dipole moment and centrifugal distortion of 3-buten-1-ol.

Marstokk KM and Mollendal H.

Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry, 35(6), 395-401 (1981)

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全球贸易项目编号

货号	GTIN
496839-1KG	04061837324208
496839-25G	04061832417288
496839-100G	04061832417271