Merck
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文件

安全信息

497312

Sigma-Aldrich

4-哌啶甲醇

97%

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别名:
4-羟甲基哌啶
经验公式（希尔记法）:
C6H13NO
CAS号:
6457-49-4
分子量:
115.17
MDL编号:
MFCD00174228
PubChem化学物质编号:
24873109
NACRES:
NA.22

质量水平

100

检测方案

97%

bp

118-120 °C/10 mmHg (lit.)

mp

55-59 °C (lit.)

SMILES字符串

OCC1CCNCC1

InChI

1S/C6H13NO/c8-5-6-1-3-7-4-2-6/h6-8H,1-5H2

InChI key

XBXHCBLBYQEYTI-UHFFFAOYSA-N

相关类别

一般描述

4-Piperidinemethanol is a cyclic secondary amine. Its standard molar enthalpies of combustion, sublimation and formation have been determined.

应用

4-Piperidinemethanol may be used in the preparation of:
  • N-tert-butoxycarbonyl-4-hydroxymethyl piperidine
  • desferrioxamine B (DFO) containing third generation triazine dendrimer
  • ethyl 3-(4-(hydroxymethyl)piperidin-1-yl)propanoate (EHMPP)
  • 4-(hydroxymethyl)piperidine-1-carbodithioic acid (HL)
  • 1-[[(1E)-2-(4-chlorophenyl)ethenyl]sulfonyl]-4-piperidinemethanol
Substrate used in solid-phase organic synthesis of a secondary amine.

象形图

Corrosion
GHS05

警示用语：

Danger

危险声明

H314

危险分类

Skin Corr. 1B

储存分类代码

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

闪点(°F)

230.0 °F - closed cup

闪点(°C)

110 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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Francis Giraud et al.
Bioorganic & medicinal chemistry letters, 19(2), 301-304 (2008-12-19)
Continuous efforts on the synthesis and structure-activity relationships (SARs) studies of modified 1-benzylamino-2-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-2-ols as antifungal agents, allowed identification of new 1-[(pyridinyl- and piperidinylmethyl)amino] derivatives with MIC(80) values ranging from 1410.0 to 23.0ngmL(-1) on Candidaalbicans. These results confirmed both the importance
Christian A Olsen et al.
Organic letters, 6(12), 1935-1938 (2004-06-05)
[reaction: see text] An expedient solid-phase synthetic approach to secondary and tertiary amines was developed. The protocol employs conversion of resin-bound amino alcohols to the corresponding iodides, followed by iodide displacement with primary or secondary amines or with unprotected amino
Synthesis, spectroscopy, and biological activity of heterobimetallic complexes containing Sn (IV) and Pd (II) with 4-(hydroxymethyl) piperidine-1-carbodithioic acid.
Anwar MT, et al.
Russ. J. Gen. Chem., 83(12), 2380-2385 (2013)
Standard molar enthalpies of formation of 2-, 3-, and 4-piperidinomethanol isomers.
da Silva MAVR and Cabral JITA
The Journal of Chemical Thermodynamics, 38(8), 1008-1012 (2006)
Jongdoo Lim et al.
Bioorganic & medicinal chemistry, 18(15), 5749-5753 (2010-07-10)
The synthesis of a third generation triazine dendrimer, 1, containing multiple, iron-sequestering desferrioxamine B (DFO) groups is described. Benzoylation of the hydroxamic acid groups of DFO and formation of a reactive dichlorotriazine provide the intermediate for reaction with the second
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