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Merck
CN

49800

D -(+)-甘油醛

≥98.0% (HPLC)

别名:

(2R)-2,3-Dihydroxypropanal, Triose

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关于此项目

经验公式(希尔记法):
C3H6O3
化学文摘社编号:
分子量:
90.08
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-217-1
Beilstein/REAXYS Number:
1720474
MDL number:
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产品名称

D -(+)-甘油醛, ≥98.0% (HPLC)

InChI key

MNQZXJOMYWMBOU-VKHMYHEASA-N

InChI

1S/C3H6O3/c4-1-3(6)2-5/h1,3,5-6H,2H2/t3-/m0/s1

SMILES string

OC[C@@H](O)C=O

assay

≥98.0% (HPLC)

impurities

≤10% water

storage temp.

2-8°C

Quality Level

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Application

D-(+)-甘油醛可用作合成以下物质的反应物:
  • (S)-高苯丙氨酸,通过胺和α-羟醛偶联生成的3-氨基-1,2-二醇的钌氧化制备。
  • β- 和γ-联烯醇,通过金属催化环化制备。联烯醇是制备对映体纯的二氢吡喃和四氢噁英(tetrahydrooxepine)的关键前体。
  • 异亚丙基D-甘油醛中间体,其控制前列腺素(PGE1)的总合成中的手性。

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chiral synthesis of prostaglandins (PGE1) from D-glyceraldehyde
Stork G and Takahashi T
Journal of the American Chemical Society, 99(4), 1275-1276 (1977)
Katarzyna Lechowicz et al.
International journal of molecular sciences, 21(16) (2020-08-13)
Lolium multiflorum/Festuca arundinacea introgression forms have been proved several times to be good models to identify key components of grass metabolism involved in the mechanisms of tolerance to water deficit. Here, for the first time, a relationship between photosynthetic and
Highly stereocontrolled one-step synthesis of anti-β-amino alcohols from organoboronic acids, amines, and α-hydroxy aldehydes
Petasis NA and Zavialov IA
Journal of the American Chemical Society, 120(45), 11798-11799 (1998)
Takayoshi Wakagi et al.
PloS one, 11(1), e0147333-e0147333 (2016-01-26)
Archaea use glycolytic pathways distinct from those found in bacteria and eukaryotes, where unique enzymes catalyze each reaction step. In this study, we isolated three isozymes of glyceraldehyde oxidoreductase (GAOR1, GAOR2 and GAOR3) from the thermoacidophilic archaeon Sulfolobus tokodaii. GAOR1-3
Metal-Catalyzed Cyclization of β-and γ-Allenols Derived from d-Glyceraldehyde- Synthesis of Enantiopure Dihydropyrans and Tetrahydrooxepines: An Experimental and Theoretical Study
Alcaide BL
Chemistry?A European Journal , 15(36), 9127-9138 (2009)

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