498270
1-氯-N,N,2-三甲基-1-丙烯胺
96%
别名:
Ghosez 试剂
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关于此项目
线性分子式:
(CH3)2C=C(Cl)N(CH3)2
化学文摘社编号:
分子量:
133.62
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
96%
InChI
1S/C6H12ClN/c1-5(2)6(7)8(3)4/h1-4H3
SMILES string
CN(C)\C(Cl)=C(\C)C
InChI key
GQIRIWDEZSKOCN-UHFFFAOYSA-N
assay
96%
refractive index
n20/D 1.453 (lit.)
bp
129-130 °C (lit.)
density
1.01 g/mL at 25 °C (lit.)
functional group
amine, chloro
storage temp.
2-8°C
Quality Level
Application
1-氯-N,N,2-三甲基-1-丙烯胺是由Ghosez开发的 酸性卤化试剂 ，其能够在严格中性条件下将羧酸转化为相应的氯化物。该方法已成功用于caloporoside、roseophilin、(-)-enniatin B、(±)-pimeloscine和(±)-meloscine的全合成。
signalword
Danger
存储类别
3 - Flammable liquids
wgk
WGK 3
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
flash_point_f
<73.4 °F - closed cup
flash_point_c
< 23 °C - closed cup
法规信息
危险化学品
此项目有
H. Bohme and H. G. Viehe, Eds.
Adv. Org. Chem., 9, 421-421 (1976)
A short total synthesis of (?)-epimeloscine and (?)-meloscine enabled by a cascade radical annulation of a divinylcyclopropane.
Zhang H, et al.
Journal of the American Chemical Society, 133(27), 10376-10378 (2011)
Total synthesis of caloporoside.
Furstner A, et al.
The Journal of Organic Chemistry, 63, 3072-3072 (1998)
?-Chloro enamines, reactive intermediates for synthesis: 1-Chloro-N,N,2-trimethylpropenylamine.
Haveaux B, et al.
Organic Syntheses, 59, 26-26 (1980)
A total synthesis of the ammonium ionophore,(?)-enniatin B.
Hu D, et al.
Tetrahedron Letters, 53(32), 4077-4079 (2012)
商品
Fluoroamidinium salts advance acid halogenation with greater stability and no oxazolones conversion compared to chlorides.
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