498785
2-甲氧基苄基氯化锌 溶液
0.5 M in THF
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关于此项目
线性分子式:
CH3OC6H4CH2ZnCl
CAS Number:
分子量:
222.00
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
浓度
0.5 M in THF
密度
0.937 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
COc1ccccc1C[Zn]Cl
InChI
1S/C8H9O.ClH.Zn/c1-7-5-3-4-6-8(7)9-2;;/h3-6H,1H2,2H3;1H;/q;;+1/p-1
InChI key
NRJJPCZGLGLMEV-UHFFFAOYSA-M
应用
2-Methoxybenzylzinc chloride can be used as:
- An intermediate in the preparation of 2,4-diamino-6-arylmethylquinazolines as possible DHFR inhibitors.
- A model organozinc compound in the Pd-catalyzed synthesis of α-aryl tertiary amides by reacting with carbamoyl chlorides.
- A substrate in the synthesis of forensically significant pyridine and pyrimidine derivatives.
法律信息
Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
靶器官
Central nervous system, Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
1.0 °F - closed cup
闪点(°C)
-17.22 °C - closed cup
法规信息
新产品
Suzuki-Miyaura and Negishi approaches to a series of forensically relevant pyridines and pyrimidines
Blachut D, et al.
Synthesis, 2011(21), 3496-3506 (2011)
A novel method of synthesis of 2, 4-diamino-6-arylmethylquinazolines using palladium (0)-catalyzed organozinc chemistry
Rosowsky A and Chen H
The Journal of Organic Chemistry, 66(22), 7522-7526 (2001)
Preparation of tertiary amides via aryl, heteroaryl, and benzyl organozinc reagents; scope and limitations
Rieke RD and Kim S
Tetrahedron Letters, 53(27), 3478-3481 (2012)
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