510556
2,2′-联嘧啶
95%
别名:
2,2′-二嘧啶
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关于此项目
经验公式（希尔记法）:
C8H6N4
化学文摘社编号:
分子量:
158.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
252-137-2
MDL number:
Assay:
95%
Form:
solid
产品名称
2,2′-联嘧啶, 95%
InChI key
HKOAFLAGUQUJQG-UHFFFAOYSA-N
InChI
1S/C8H6N4/c1-3-9-7(10-4-1)8-11-5-2-6-12-8/h1-6H
SMILES string
c1cnc(nc1)-c2ncccn2
assay
95%
form
solid
mp
112-116 °C (lit.)
Quality Level
Application
2,2′-双嘧啶 (bpym) 可作为配体用于合成下列配合物：[Mn 2 (bpym) (N 3 ) 4 ]，其中 N 3 = 叠氮化物
- [Fe (bt) (NCS) 2 ] 2 bpym，其中 bt = 2,2′-bi-2-噻唑啉和 NCS = 异氰酸酯
- 钴 2 {[N (CN) 2 ] 4 bpym}·H 2 O 和钴 {[N (CN) 2 ] 2 bpym}·H 2 O
- [MoM (CO) 8 (bpym)]，其中 M = Cr,Mo,W
General description
2,2'-双嘧啶 (bpym) 是一种桥接、π 离域的双螯合配体，可与金属离子形成单核和双核配合物。2,2′ 的光致发光特性-研究了双嘧啶/镧系离子配合物。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Mehdi Elsayed Moussa et al.
European journal of inorganic chemistry, 2016(28), 4538-4541 (2016-11-22)
The three-component reaction of the tetrahedral diphosphorus complex [Cp
Four bridging bis chelate ligands with very low lying. Π* orbitals. MO perturbation calculations, electrochemistry, and spectroscopy of mononuclear and binuclear group 6 metal tetracarbonyl complexes.
Kaim W and Kohlmann S.
Inorganic Chemistry, 26(1), 68-77 (1987)
Two-step spin crossover in the new dinuclear compound [Fe(bt)(NCS)2]2bpym, with bt=2,2'-bi-2-thiazoline and bpym=2,2'-bipyrimidine: experimental investigation and theoretical approach.
Real JA, et al.
Journal of the American Chemical Society, 114(12), 4650-4658 (1992)
Synthesis, Structure, and Magnetic Properties of Co2{[N(CN)2]4bpym}?H2O and M{[N(CN)2]2bpym}?H2O (M= Mn, Fe, Co; bpym= 2,2'-Bipyrimidine).
Marshall SR, et al.
Inorganic Chemistry, 39(9), 1969-1973 (2000)
Structure and photophysical behavior of 2,2'-bipyrimidine/lanthanide ion complexes in various environments.
Bekiari V, et al.
Journal of Luminescence, 128(3), 481-488 (2008)
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