510963
2-[(三甲基硅基)乙炔基]苯胺
97%
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关于此项目
线性分子式:
(CH3)3SiC≡CC6H4NH2
化学文摘社编号:
分子量:
189.33
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
2-[(三甲基硅基)乙炔基]苯胺, 97%
InChI
1S/C11H15NSi/c1-13(2,3)9-8-10-6-4-5-7-11(10)12/h4-7H,12H2,1-3H3
SMILES string
C[Si](C)(C)C#Cc1ccccc1N
InChI key
ISXSBRZDPKQYSC-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.564 (lit.)
bp
120 °C/0.1 mmHg (lit.)
density
0.94 g/mL at 25 °C (lit.)
Quality Level
Application
2-[(Trimethylsilyl)ethynyl]aniline (2-(2-Trimethylsilylethynyl)aniline) may be used in the synthesis of:
- N-(2-trimethylsilylethynylphenyl)methanesulfonamide
- 8-(2-((trimethylsilyl)ethynyl)phenylamino)-7H-naphtho[1,8-bc]acridin-7-one
- 2-phenyl-4-alkoxy quinolines
General description
2-[(Trimethylsilyl)ethynyl]aniline is a 2-ethynylaniline derivative that can be prepared by the palladium-catalyzed reaction between 2-bromonitrobenzene and trimethylsilylacetylene.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Synthesis and Characterization of 8-(2-((Trimethylsilyl) ethynyl) phenylamino)-7H-naphtho [1,8-bc] acridin-7-one.
Li L, et al.
Synthetic Communications, 38(24), 4415-4425 (2008)
Condensed heteroaromatic ring systems. XIII. One-step synthesis of 2-substituted 1-methylsulfonylindoles from N-(2-halophenyl) methanesulfonamides.
Sakamoto T, et al.
Chemical & Pharmaceutical Bulletin, 36, 1305-1308 (1988)
Marella A, et al.
Saudi Pharmaceutical Journal : SPJ : The Official Publication of the Saudi Pharmaceutical Society, 21(1), 1-2 (2013)
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