514330
甲基锂 溶液
3.1 M in diethoxymethane
别名:
Lithium methanide, MeLi
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关于此项目
经验公式（希尔记法）:
CH3Li
化学文摘社编号:
分子量:
21.98
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587162
Concentration:
3.1 M in diethoxymethane
Form:
liquid
form
liquid
Quality Level
concentration
3.1 M in diethoxymethane
density
0.846 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li]C
InChI
1S/CH3.Li/h1H3;
InChI key
DVSDBMFJEQPWNO-UHFFFAOYSA-N
Application
在钛酸四异丙酯存在下，以2-(2-羟基芳基)醇（HAROL）配体为催化剂，甲基锂溶液（3.1 M，溶剂为二乙氧基甲烷）可以与苯甲醛发生1,2-加成，形成 (S)-1-苯乙-1-醇。
Packaging
建议将25 mL Sure/Seal™ 瓶作为一次性瓶使用。 反复穿刺可能导致产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Disclaimer
产品可能在瓶底形成固体或沉淀物。
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signalword
Danger
hcodes
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 1
flash_point_f
5.0 °F - closed cup
flash_point_c
-15 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react. 1
法规信息
危险化学品
此项目有
Chiral 2-(2-hydroxyaryl) alcohols (HAROLs) with a 1, 4-diol scaffold as a new family of ligands and organocatalysts.
Dilek O, et al.
Tetrahedron, 74(2), 268-286 (2018)
Erik Selander et al.
Proceedings of the National Academy of Sciences of the United States of America, 112(20), 6395-6400 (2015-04-29)
Interactions among microscopic planktonic organisms underpin the functioning of open ocean ecosystems. With few exceptions, these organisms lack advanced eyes and thus rely largely on chemical sensing to perceive their surroundings. However, few of the signaling molecules involved in interactions
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 514330-100ML | 04061832492872 |
| 514330-4X25ML | 04061837882210 |
| 514330-1L | 04061837882203 |