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516031

(S)-(-)-N-Z-氮杂环丙烷-2-羧酸甲酯

Name: (<I>S</I>)-(-)-<I>N</I>-Z-氮杂环丙烷-2-羧酸甲酯
Brand: ALDRICH

96%

别名:

(2S)-1,2-Aziridinedicarboxylic acid 2-methyl 1-(phenylmethyl) ester, (S)-N-Cbz-aziridine-2-carboxylic acid methyl ester, 1-Benzyl 2-methyl (S)-(−)-1,2-aziridinedicarboxylate, Methyl (S)-N-Cbz-aziridine-2-carboxylate

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关于此项目

经验公式（希尔记法）:

C₁₂H₁₃NO₄

化学文摘社编号:

104597-98-0

分子量:

235.24

NACRES:

NA.22

PubChem Substance ID:

24873860

UNSPSC Code:

12352005

MDL number:

MFCD06799020

Assay:

96%

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属性

Quality Level

200

assay

96%

optical activity

[α]20/D −25°, c = 1 in toluene

refractive index

n20/D 1.519 (lit.)

bp

160-165 °C/2 mmHg (lit.)

density

1.19 g/mL at 25 °C (lit.)

functional group

ester, phenyl

SMILES string

COC(=O)C1CN1C(=O)OCc2ccccc2

InChI

1S/C12H13NO4/c1-16-11(14)10-7-13(10)12(15)17-8-9-5-3-2-4-6-9/h2-6,10H,7-8H2,1H3/t10-,13?/m0/s1

InChI key

GTZJUBQWCWZING-NKUHCKNESA-N

说明

General description

Methyl (S)-(−)-N-Z-aziridine-2-carboxylate is commonly used as an electrophilic aziridination reagent in organic synthesis. It is a chiral bicyclic lactam reagent that can be used for the synthesis of chiral aziridines from alkenes. The reagent is particularly useful in the synthesis of chiral building blocks.

Application

Methyl (S)-(−)-N-Z-aziridine-2-carboxylate can be used as a reactant in the total synthesis of α-C-mannosyltryptophan (C-Man-Trp), a naturally occurring C-glycosylamino acid. It is also used in the preparation of optically active aziridine derivatives.

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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全球贸易项目编号

货号	GTIN
516031-5G	04061837727672