516031
(S)-(-)-N-Z-氮杂环丙烷-2-羧酸甲酯
96%
别名:
(2S)-1,2-Aziridinedicarboxylic acid 2-methyl 1-(phenylmethyl) ester, (S)-N-Cbz-aziridine-2-carboxylic acid methyl ester, 1-Benzyl 2-methyl (S)-(−)-1,2-aziridinedicarboxylate, Methyl (S)-N-Cbz-aziridine-2-carboxylate
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关于此项目
经验公式（希尔记法）:
C12H13NO4
化学文摘社编号:
分子量:
235.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
(S)-(-)-N-Z-氮杂环丙烷-2-羧酸甲酯, 96%
InChI
1S/C12H13NO4/c1-16-11(14)10-7-13(10)12(15)17-8-9-5-3-2-4-6-9/h2-6,10H,7-8H2,1H3/t10-,13?/m0/s1
SMILES string
COC(=O)C1CN1C(=O)OCc2ccccc2
InChI key
GTZJUBQWCWZING-NKUHCKNESA-N
assay
96%
optical activity
[α]20/D −25°, c = 1 in toluene
refractive index
n20/D 1.519 (lit.)
bp
160-165 °C/2 mmHg (lit.)
density
1.19 g/mL at 25 °C (lit.)
functional group
ester
phenyl
Quality Level
Application
Methyl (S)-(−)-N-Z-aziridine-2-carboxylate can be used as a reactant in the total synthesis of α-C-mannosyltryptophan (C-Man-Trp), a naturally occurring C-glycosylamino acid. It is also used in the preparation of optically active aziridine derivatives.
General description
Methyl (S)-(−)-N-Z-aziridine-2-carboxylate is commonly used as an electrophilic aziridination reagent in organic synthesis. It is a chiral bicyclic lactam reagent that can be used for the synthesis of chiral aziridines from alkenes. The reagent is particularly useful in the synthesis of chiral building blocks.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
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