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Merck
CN

52270

Sigma-Aldrich

1-十六烷硫醇

≥95.0% (GC)

别名:

十六烷基硫醇, 十六硫醇, 正十六硫醇

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关于此项目

线性分子式:
CH3(CH2)15SH
化学文摘社编号:
分子量:
258.51
Beilstein:
1748495
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案

≥95.0% (GC)

折射率

n20/D 1.462 (lit.)
n20/D 1.464

沸点

184-191 °C/7 mmHg (lit.)

mp

18-20 °C (lit.)

转变温度

solidification point 15-18 °C(lit.)

密度

0.84 g/mL at 25 °C (lit.)

官能团

thiol

SMILES字符串

CCCCCCCCCCCCCCCCS

InChI

1S/C16H34S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h17H,2-16H2,1H3

InChI key

ORTRWBYBJVGVQC-UHFFFAOYSA-N

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一般描述

1-十六硫醇 (HDT) 在金表面易形成自组装单分子膜 (SAMs)。研究由 HDT 和 3-巯基丙酸组成的二元自组装膜在 Au (111) 表面的相分离特性。利用原子力显微镜 (AFM) 研究金表面与表面活性剂 SAM 之间的相互作用。

应用

1-十六硫醇已用于制备胆固醇-PIE12-三聚体和烷基-PIE12-三聚体(PIE12-三聚体 = 蛋白酶抗性三聚体 D 肽抑制剂)。它可用于银纳米线的功能化。

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

215.6 °F - closed cup

闪点(°C)

102 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Langmuir-Blodgett silver nanowire monolayers for molecular sensing using surface-enhanced Raman spectroscopy.
Tao A, et al.
Nano Letters, 3(9), 1229-1233 (2003)
Kishan Rijal et al.
Langmuir : the ACS journal of surfaces and colloids, 23(12), 6856-6863 (2007-05-08)
We describe a cantilever-based method for measuring the self-assembly of alkanethiols on a gold surface in a flow system that permits easy step changes in concentration and acquire a continuous in situ measure of the resulting chemisorption through the change
J Christopher Love et al.
Journal of the American Chemical Society, 124(8), 1576-1577 (2002-02-21)
This paper describes microcontact printing (muCP) of long-chain alkanethiolates on palladium, followed by solution-phase etching with an iron(III)-based etchant, to make patterned structures. The commonly used soft-lithographic procedure for fabricating microstructures-muCP of SAMs on gold-has three shortcomings: a significant surface
Catarina Gonçalves et al.
Biomacromolecules, 8(2), 392-398 (2007-02-13)
The amphiphilic molecule dextrin-VA-SC16 (dexC16) was synthesized and studied in this work. DexC16 has a hydrophilic dextrin backbone with grafted acrylate groups (VA) substituted with hydrophobic 1-hexadecanethiol (C16). A versatile synthetic method was developed allowing control of the dextrin degree
Assembly and alignment of metallic nanorods on surfaces with patterned wettability.
Shuhong Liu et al.
Small (Weinheim an der Bergstrasse, Germany), 2(12), 1448-1453 (2006-12-29)

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