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Merck
CN

52270

1-十六烷硫醇

≥95.0% (GC)

别名:

十六烷基硫醇, 十六硫醇, 正十六硫醇

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关于此项目

线性分子式:
CH3(CH2)15SH
化学文摘社编号:
分子量:
258.51
Beilstein:
1748495
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案

≥95.0% (GC)

折射率

n20/D 1.462 (lit.)
n20/D 1.464

沸点

184-191 °C/7 mmHg (lit.)

mp

18-20 °C (lit.)

转变温度

solidification point 15-18 °C(lit.)

密度

0.84 g/mL at 25 °C (lit.)

官能团

thiol

SMILES字符串

CCCCCCCCCCCCCCCCS

InChI

1S/C16H34S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h17H,2-16H2,1H3

InChI key

ORTRWBYBJVGVQC-UHFFFAOYSA-N

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相关类别

一般描述

1-十六硫醇 (HDT) 在金表面易形成自组装单分子膜 (SAMs)。研究由 HDT 和 3-巯基丙酸组成的二元自组装膜在 Au (111) 表面的相分离特性。利用原子力显微镜 (AFM) 研究金表面与表面活性剂 SAM 之间的相互作用。

应用

1-十六硫醇已用于制备胆固醇-PIE12-三聚体和烷基-PIE12-三聚体(PIE12-三聚体 = 蛋白酶抗性三聚体 D 肽抑制剂)。它可用于银纳米线的功能化。

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

215.6 °F - closed cup

闪点(°C)

102 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Lower hole-injection barrier between pentacene and a 1-hexadecanethiol-modified gold substrate with a lowered work function.
Hong K, et al.
Organic Electronics, 9(1), 21-29 (2008)
X Torrelles et al.
Langmuir : the ACS journal of surfaces and colloids, 20(21), 9396-9402 (2004-10-06)
The c(4 x 2) structure of C16H33SH alkanethiol monolayers self-assembled on Au(111) has been studied by grazing incidence X-ray diffraction. This structure coexists on the surface with the (radical3x radical3)R30 degrees phase. The structural refinement of the c(4 x 2)
Jialin Wang et al.
Langmuir : the ACS journal of surfaces and colloids, 24(15), 7889-7896 (2008-06-26)
An atomic force microscope (AFM) was used to measure the forces between gold surfaces with and without hydrophobizing them by the self-assembly of 1-hexadecanethiol. The forces measured between bare gold surfaces were fitted to the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory with a
Assembly and alignment of metallic nanorods on surfaces with patterned wettability.
Shuhong Liu et al.
Small (Weinheim an der Bergstrasse, Germany), 2(12), 1448-1453 (2006-12-29)
J Nicholas Francis et al.
Bioconjugate chemistry, 23(6), 1252-1258 (2012-05-02)
The highly conserved HIV-1 gp41 "pocket" region is a promising target for inhibiting viral entry. PIE12-trimer is a protease-resistant trimeric d-peptide inhibitor that binds to this pocket and potently blocks HIV entry. PIE12-trimer also possesses a reserve of binding energy

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