52270
1-十六烷硫醇
≥95.0% (GC)
别名:
十六烷基硫醇, 十六硫醇, 正十六硫醇
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关于此项目
线性分子式:
CH3(CH2)15SH
化学文摘社编号:
分子量:
258.51
Beilstein:
1748495
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
≥95.0% (GC)
折射率
n20/D 1.462 (lit.)
n20/D 1.464
沸点
184-191 °C/7 mmHg (lit.)
mp
18-20 °C (lit.)
转变温度
solidification point 15-18 °C(lit.)
密度
0.84 g/mL at 25 °C (lit.)
官能团
thiol
SMILES字符串
CCCCCCCCCCCCCCCCS
InChI
1S/C16H34S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h17H,2-16H2,1H3
InChI key
ORTRWBYBJVGVQC-UHFFFAOYSA-N
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一般描述
1-十六硫醇 (HDT) 在金表面易形成自组装单分子膜 (SAMs)。研究由 HDT 和 3-巯基丙酸组成的二元自组装膜在 Au (111) 表面的相分离特性。利用原子力显微镜 (AFM) 研究金表面与表面活性剂 SAM 之间的相互作用。
应用
1-十六硫醇已用于制备胆固醇-PIE12-三聚体和烷基-PIE12-三聚体（PIE12-三聚体 = 蛋白酶抗性三聚体 D 肽抑制剂）。它可用于银纳米线的功能化。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
215.6 °F - closed cup
闪点(°C)
102 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Langmuir : the ACS journal of surfaces and colloids, 20(21), 9396-9402 (2004-10-06)
The c(4 x 2) structure of C16H33SH alkanethiol monolayers self-assembled on Au(111) has been studied by grazing incidence X-ray diffraction. This structure coexists on the surface with the (radical3x radical3)R30 degrees phase. The structural refinement of the c(4 x 2)
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Organic Electronics, 9(1), 21-29 (2008)
J Christopher Love et al.
Journal of the American Chemical Society, 124(8), 1576-1577 (2002-02-21)
This paper describes microcontact printing (muCP) of long-chain alkanethiolates on palladium, followed by solution-phase etching with an iron(III)-based etchant, to make patterned structures. The commonly used soft-lithographic procedure for fabricating microstructures-muCP of SAMs on gold-has three shortcomings: a significant surface
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Biomacromolecules, 8(2), 392-398 (2007-02-13)
The amphiphilic molecule dextrin-VA-SC16 (dexC16) was synthesized and studied in this work. DexC16 has a hydrophilic dextrin backbone with grafted acrylate groups (VA) substituted with hydrophobic 1-hexadecanethiol (C16). A versatile synthetic method was developed allowing control of the dextrin degree
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