52270
1-十六烷硫醇
≥95.0% (GC)
别名:
十六烷基硫醇, 十六硫醇, 正十六硫醇
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关于此项目
线性分子式:
CH3(CH2)15SH
化学文摘社编号:
分子量:
258.51
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-846-6
Beilstein/REAXYS Number:
1748495
MDL number:
Assay:
≥95.0% (GC)
InChI key
ORTRWBYBJVGVQC-UHFFFAOYSA-N
InChI
1S/C16H34S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h17H,2-16H2,1H3
SMILES string
CCCCCCCCCCCCCCCCS
assay
≥95.0% (GC)
refractive index
n20/D 1.462 (lit.), n20/D 1.464
bp
184-191 °C/7 mmHg (lit.)
mp
18-20 °C (lit.)
transition temp
solidification point 15-18 °C(lit.)
density
0.84 g/mL at 25 °C (lit.)
functional group
thiol
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Application
1-十六硫醇已用于制备胆固醇-PIE12-三聚体和烷基-PIE12-三聚体（PIE12-三聚体 = 蛋白酶抗性三聚体 D 肽抑制剂）。它可用于银纳米线的功能化。
General description
1-十六硫醇 (HDT) 在金表面易形成自组装单分子膜 (SAMs)。研究由 HDT 和 3-巯基丙酸组成的二元自组装膜在 Au (111) 表面的相分离特性。利用原子力显微镜 (AFM) 研究金表面与表面活性剂 SAM 之间的相互作用。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
215.6 °F - closed cup
flash_point_c
102 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Lower hole-injection barrier between pentacene and a 1-hexadecanethiol-modified gold substrate with a lowered work function.
Hong K, et al.
Organic Electronics, 9(1), 21-29 (2008)
X Torrelles et al.
Langmuir : the ACS journal of surfaces and colloids, 20(21), 9396-9402 (2004-10-06)
The c(4 x 2) structure of C16H33SH alkanethiol monolayers self-assembled on Au(111) has been studied by grazing incidence X-ray diffraction. This structure coexists on the surface with the (radical3x radical3)R30 degrees phase. The structural refinement of the c(4 x 2)
Jialin Wang et al.
Langmuir : the ACS journal of surfaces and colloids, 24(15), 7889-7896 (2008-06-26)
An atomic force microscope (AFM) was used to measure the forces between gold surfaces with and without hydrophobizing them by the self-assembly of 1-hexadecanethiol. The forces measured between bare gold surfaces were fitted to the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory with a
Langmuir-Blodgett silver nanowire monolayers for molecular sensing using surface-enhanced Raman spectroscopy.
Tao A, et al.
Nano Letters, 3(9), 1229-1233 (2003)
Dana M Rosu et al.
Langmuir : the ACS journal of surfaces and colloids, 25(2), 919-923 (2008-12-25)
Infrared spectroscopic ellipsometry was used for determination of molecular orientation and for lateral homogeneity studies of organic monolayers on GaAs and Au, the organic layer being either octanedithiol or hexadecanethiol (HDT). The laterally resolved measurements were performed with the infrared
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