524336
4-溴吲哚
96%
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关于此项目
经验公式（希尔记法）:
C8H6BrN
化学文摘社编号:
分子量:
196.04
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
96%
折射率
n20/D 1.655 (lit.)
沸点
283-285 °C (lit.)
密度
1.563 g/mL at 25 °C (lit.)
官能团
bromo
SMILES字符串
Brc1cccc2[nH]ccc12
InChI
1S/C8H6BrN/c9-7-2-1-3-8-6(7)4-5-10-8/h1-5,10H
InChI key
GRJZJFUBQYULKL-UHFFFAOYSA-N
应用
4-溴吲哚可用于合成：
- clavicipitic acid，一种麦角生物碱
- 4-溴氢色氨酸
- 3-吲哚基乙腈衍生物
- 海生生物碱双氰菊酯 B
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
230.0 °F - closed cup
闪点(°C)
110 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Andrew K Pitts et al.
Angewandte Chemie (International ed. in English), 54(18), 5451-5455 (2015-02-24)
A sequential CH functionalization strategy for the synthesis of the marine alkaloid dictyodendrin B is reported. Our synthesis begins from commercially available 4-bromoindole and involves six direct functionalizations around the heteroarene core as part of a gram-scale strategy towards the natural
S Liras et al.
Journal of the American Chemical Society, 123(25), 5918-5924 (2001-06-21)
Concise syntheses of the Ergot alkaloids rugulovasine A (3a), rugulovasine B (3b), and setoclavine (2) have been completed by strategies that feature inter- and intramolecular vinylogous Mannich reactions as the key steps. Thus, the first synthesis of 3a,b commenced with
Optically active total synthesis of clavicipitic acid.
Yokoyama Y, et al.
The Journal of Organic Chemistry, 60(6), 1486-1487 (1995)
Metal-halogen exchange of bromoindoles. A route to substituted indoles.
Moyer MP, et al.
The Journal of Organic Chemistry, 51(26), 5106- 5110 (1986)
Chaitany Jayprakash Raorane et al.
Biomolecules, 10(8) (2020-08-23)
Multi-drug resistant Acinetobacter baumannii is well-known for its rapid acclimatization in hospital environments. The ability of the bacterium to endure desiccation and starvation on dry surfaces for up to a month results in outbreaks of health care-associated infections. Previously, indole
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