52435
(Z)-1,4-己二烯
≥99.0%
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关于此项目
经验公式（希尔记法）:
C6H10
化学文摘社编号:
分子量:
82.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
230-783-6
Beilstein/REAXYS Number:
1839519
MDL number:
Assay:
≥99.0%
InChI key
PRBHEGAFLDMLAL-XQRVVYSFSA-N
InChI
1S/C6H10/c1-3-5-6-4-2/h3-4,6H,1,5H2,2H3/b6-4-
SMILES string
C\C=C/CC=C
assay
≥99.0%
refractive index
n20/D 1.415
bp
65-66 °C (lit.)
density
0.707 g/mL at 20 °C (lit.)
functional group
allyl
Quality Level
General description
cis-1,4-Hexadiene can be synthesized from the cobalt-catalyzed reaction between butadiene and ethylene. The reaction of this hydrocarbon with Fe(CO)5 affords the trans-1,3-hexadiene-iron tricarbonyl complex (I), plus a small amount of the trans,trans-2,4-hexadiene complex(II). Mechanism of the conversion of cis-1,4-hexadiene to trans-2-methyl-1,3-pentadiene, via rearrangement in the presence of a nickel catalyst has been investigated.
signalword
Danger
hcodes
pcodes
Hazard Classifications
Acute Tox. 3 Oral - Asp. Tox. 1 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-50.8 °F - closed cup
flash_point_c
-46 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Nickel-promoted methylvinylcyclopropane rearrangements. Mechanistic relevance to the cis-1, 4-hexadiene to 2-methyl-1, 3-pentadiene isomerization.
Pinke PA, et al.
Journal of the American Chemical Society, 96(13), 4229-4234 (1974)
Reaction of cis-1, 4-Hexadiene with Iron Pentacarbonyl.
Kuji J and Iwamoto M.
Bulletin of the Chemical Society of Japan, 41(6), 1483-1484 (1968)
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