52730
六甲基磷酰三胺
purum, ≥98.0% (GC)
别名:
HMPA, 三(二甲氨基)氧膦, 六甲基磷酸三胺
蒸汽密度
6.18 (vs air)
质量水平
蒸汽压
0.07 mmHg ( 25 °C)
等级
purum
方案
≥98.0% (GC)
杂质
≤2.0% water (Karl Fischer)
折射率
n20/D 1.459 (lit.)
n20/D 1.459
沸点
230-232 °C/740 mmHg (lit.)
mp
7 °C (lit.)
密度
1.03 g/mL at 25 °C (lit.)
官能团
phosphoramide
SMILES字符串
CN(C)P(=O)(N(C)C)N(C)C
InChI
1S/C6H18N3OP/c1-7(2)11(10,8(3)4)9(5)6/h1-6H3
InChI key
GNOIPBMMFNIUFM-UHFFFAOYSA-N
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警示用语：
Danger
危险声明
危险分类
Carc. 1B - Eye Dam. 1 - Muta. 1B - Skin Corr. 1C
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
291.2 °F - closed cup
闪点(°C)
144 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Kristopher J Kolonko et al.
The Journal of organic chemistry, 75(18), 6163-6172 (2010-08-26)
A variety of multinuclear NMR techniques, in combination with X-ray diffraction methods, were used to probe the solution structure of α-aryl lithium enolates of bis(4-fluorobenzyl) ketone (1-H), phenyl 4-fluorobenzyl ketone (2-H), and N,N-dimethyl 4-fluorophenylacetamide (3-H) in ethereal solvents and in
Ge Gao et al.
Proceedings of the National Academy of Sciences of the United States of America, 101(15), 5417-5420 (2004-03-18)
It is found that the addition of hexamethylphosphoramide to the solution of an alkyne, Et(2)Zn, and (S)-1,1'-bi-2-naphthol in methylene chloride allows the generation of an alkynylzinc at room temperature and shows highly enantioselective additions to aldehydes. The mild condition for
Samarium diiodide-induced reductive cross-coupling of nitrones with aldehydes and ketones.
Géraldine Masson et al.
Angewandte Chemie (International ed. in English), 41(10), 1772-1775 (2002-05-17)
Wojciech Bartkowiak et al.
Journal of molecular modeling, 11(4-5), 317-322 (2005-07-12)
In this work, for the first time, a theoretical approach to describing the influence of hydrogen-bond formation on the electronic absorption spectrum and nonlinear optical properties of an aminobenzodifuranone derivative (ABF) that exhibits the largest positive solvatochromic shift compared to
Knud Nairz et al.
Genome biology, 5(10), R83-R83 (2004-10-06)
We report the use of the cross-linking drug hexamethylphosphoramide (HMPA), which introduces small deletions, as a mutagen suitable for reverse genetics in the model organism Drosophila melanogaster. A compatible mutation-detection method based on resolution of PCR fragment-length polymorphisms on standard
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