52730
六甲基磷酰三胺
purum, ≥98.0% (GC)
别名:
HMPA, 三(二甲氨基)氧膦, 六甲基磷酸三胺
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关于此项目
线性分子式:
[(CH3)2N]3PO
化学文摘社编号:
分子量:
179.20
UNSPSC Code:
12352111
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-653-8
Beilstein/REAXYS Number:
1099903
MDL number:
产品名称
六甲基磷酰三胺, purum, ≥98.0% (GC)
InChI key
GNOIPBMMFNIUFM-UHFFFAOYSA-N
InChI
1S/C6H18N3OP/c1-7(2)11(10,8(3)4)9(5)6/h1-6H3
SMILES string
CN(C)P(=O)(N(C)C)N(C)C
vapor density
6.18 (vs air)
vapor pressure
0.07 mmHg ( 25 °C)
grade
purum
assay
≥98.0% (GC)
impurities
≤2.0% water (Karl Fischer)
refractive index
n20/D 1.459 (lit.)
n20/D 1.459
bp
230-232 °C/740 mmHg (lit.)
mp
7 °C (lit.)
density
1.03 g/mL at 25 °C (lit.)
functional group
phosphoramide
Quality Level
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signalword
Danger
hcodes
Hazard Classifications
Carc. 1B - Eye Dam. 1 - Muta. 1B - Skin Corr. 1C
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
291.2 °F - closed cup
flash_point_c
144 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Drug-HPMA-HuIg conjugates effective against human solid cancer.
Blanka Ríhová et al.
Advances in experimental medicine and biology, 519, 125-143 (2003-04-05)
Anthony J Pearson et al.
Organic letters, 6(13), 2121-2124 (2004-06-18)
[reaction: see text] Vicinal stereocontrol during nucleophilic addition of tert-butyl lithiopropionate to eta(6)-anisole chromium tricarbonyl complexes with differing para substituents has been studied. Excellent vicinal double stereoinduction (>99:1) was observed when the para substituent was Si(CH(3))(3), and this has been
Robert B Grossman et al.
The Journal of organic chemistry, 68(3), 871-874 (2003-02-01)
Hexamethylphosphorous triamide (HMPT) and other phosphoramidites and phosphites have been found to be efficient catalysts for the Michael reaction of alkenones and alkynones with malonates, alpha-cyano esters, beta-keto esters, and nitro compounds. The relatively nontoxic, easily hydrolyzed HMPT catalyzes the
Knud Nairz et al.
Genome biology, 5(10), R83-R83 (2004-10-06)
We report the use of the cross-linking drug hexamethylphosphoramide (HMPA), which introduces small deletions, as a mutagen suitable for reverse genetics in the model organism Drosophila melanogaster. A compatible mutation-detection method based on resolution of PCR fragment-length polymorphisms on standard
Bahar Zarabi et al.
Pharmaceutical research, 26(5), 1121-1129 (2009-01-23)
To evaluate the tumor targeting potential of N-(2-hydroxypropyl)methacrylamide (HPMA) copolymer-gadolinium(Gd)-RGDfK conjugates by magnetic resonance (MR) T1-mapping. HPMA copolymers with and without RGDfK were synthesized to incorporate side chains for Gd chelation. The conjugates were characterized by their side-chain contents and
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