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52730

六甲基磷酰三胺

Name: 六甲基磷酰三胺
Brand: ALDRICH

purum, ≥98.0% (GC)

别名:

HMPA, 三(二甲氨基)氧膦, 六甲基磷酸三胺

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关于此项目

线性分子式:

[(CH₃)₂N]₃PO

化学文摘社编号:

680-31-9

分子量:

179.20

UNSPSC Code:

12352111

NACRES:

NA.22

PubChem Substance ID:

57651380

EC Number:

211-653-8

Beilstein/REAXYS Number:

1099903

MDL number:

MFCD00008303

Assay:

≥98.0% (GC)

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属性

vapor density

6.18 (vs air)

Quality Level

100

vapor pressure

0.07 mmHg ( 25 °C)

grade

purum

assay

≥98.0% (GC)

impurities

≤2.0% water (Karl Fischer)

refractive index

n20/D 1.459

bp

230-232 °C/740 mmHg (lit.)

mp

7 °C (lit.)

density

1.03 g/mL at 25 °C (lit.)

functional group

phosphoramide

SMILES string

CN(C)P(=O)(N(C)C)N(C)C

InChI

1S/C6H18N3OP/c1-7(2)11(10,8(3)4)9(5)6/h1-6H3

InChI key

GNOIPBMMFNIUFM-UHFFFAOYSA-N

说明

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pictograms

GHS08,GHS05

signalword

Danger

hcodes

H314,H340,H350

pcodes

P202 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Carc. 1B - Eye Dam. 1 - Muta. 1B - Skin Corr. 1C

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

291.2 °F - closed cup

flash_point_c

144 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Structure and dynamics of α-aryl amide and ketone enolates: THF, PMDTA, TMTAN, HMPA, and crypt-solvated lithium enolates, and comparison with phosphazenium analogues.

Kristopher J Kolonko et al.

The Journal of organic chemistry, 75(18), 6163-6172 (2010-08-26)

A variety of multinuclear NMR techniques, in combination with X-ray diffraction methods, were used to probe the solution structure of α-aryl lithium enolates of bis(4-fluorobenzyl) ketone (1-H), phenyl 4-fluorobenzyl ketone (2-H), and N,N-dimethyl 4-fluorophenylacetamide (3-H) in ethereal solvents and in

Highly enantioselective alkyne additions to aldehydes in the presence of 1,1'-bi-2-naphthol and hexamethylphosphoramide.

Ge Gao et al.

Proceedings of the National Academy of Sciences of the United States of America, 101(15), 5417-5420 (2004-03-18)

It is found that the addition of hexamethylphosphoramide to the solution of an alkyne, Et(2)Zn, and (S)-1,1'-bi-2-naphthol in methylene chloride allows the generation of an alkynylzinc at room temperature and shows highly enantioselective additions to aldehydes. The mild condition for

[Synthesis of substituted 3H-indole quaternary ammonium salt and study on its interaction with bovine serum albumin by fluorescence].

Tong-kuan Xu et al.

Guang pu xue yu guang pu fen xi = Guang pu, 25(6), 857-860 (2005-10-06)

A substituted 3H-indole quaternary ammonium molecule was designed and synthesized using hexamethylphosphoramide (HMPA) as a solvent. The products were purified and characterized by IR, 1H-NMR, MS and elemental analysis. The binding reaction of this compound with bovine serum albumin (BSA)

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全球贸易项目编号

货号	GTIN
766534-5G	04061832763514
52730-100ML-F	04061838128317
52730-500ML-F	04061832556956
52730-25ML-F	04061832556949