529249
2-氯-1,3-二甲基氯化咪唑啉
for peptide synthesis
别名:
2-氯-4,5-二氢-1,3-二甲基-1 H -氯化咪唑, DMC
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关于此项目
经验公式（希尔记法）:
C5H10Cl2N2
化学文摘社编号:
分子量:
169.05
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
2-氯-1,3-二甲基氯化咪唑啉,
form
crystalline
Quality Level
reaction suitability
reaction type: Coupling Reactions
mp
133-140 °C (lit.)
application(s)
peptide synthesis
functional group
chloro
SMILES string
[Cl-].CN1CC[N+](C)=C1Cl
InChI
1S/C5H10ClN2.ClH/c1-7-3-4-8(2)5(7)6;/h3-4H2,1-2H3;1H/q+1;/p-1
InChI key
AEBBXVHGVADBHA-UHFFFAOYSA-M
Application
用于 macroviracin A、cycloviracin B1 和环硅烷全合成的活化剂。
合成试剂：
标记葡萄糖作为支链寡糖合成的中间体
荧光化学传感器
1,2-二胺作为共激活剂相关精氨酸甲基转移酶 1 的抑制剂
变构葡萄糖激酶激活剂
用于合成以下物质的反应物：
伯胺中的有机叠氮化物
aza-Henry 反应试剂
标记葡萄糖作为支链寡糖合成的中间体
荧光化学传感器
1,2-二胺作为共激活剂相关精氨酸甲基转移酶 1 的抑制剂
变构葡萄糖激酶激活剂
用于合成以下物质的反应物：
伯胺中的有机叠氮化物
aza-Henry 反应试剂
wgk
WGK 3
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
商品
N-Acylimidazoles and carbonylimidazoles are reactive intermediates used for amino compound acylation, surpassing DCC as coupling reagents.
Shunya Takahashi et al.
The Journal of organic chemistry, 69(13), 4509-4515 (2004-06-19)
The C(2)-symmetric macrodiolide core 2 of an antiviral agent, macroviracin A (1), was constructed in a single step by the intermolecular macrodimerization of C(22)-hydroxy carboxylic acid 3 with 2-chloro-1,3-dimethylimidazolinium chloride and DMAP in the presence of sodium hydride (NaH). The
Alois Fürstner et al.
Journal of the American Chemical Society, 125(43), 13132-13142 (2003-10-23)
The first total synthesis of the antivirally active glycolipid cycloviracin B(1) (1) is described. The approach is based on a two-directional synthesis strategy which constructs the C(2)()-symmetrical macrodiolide core of the target by an efficient template-directed macrodilactonization reaction promoted by
Journal of Organometallic Chemistry, 686, 175-182 (2003)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 529249-100G | 04061833548158 |
| 529249-5G | 04061832557977 |
| 529249-25G | 04061832557960 |