Quality Level
assay
≥95.0%
refractive index
n20/D 1.395
bp
66-68 °C (lit.)
density
0.681 g/mL at 20 °C (lit.)
SMILES string
CC\C=C/CC
InChI
1S/C6H12/c1-3-5-6-4-2/h5-6H,3-4H2,1-2H3/b6-5-
InChI key
ZQDPJFUHLCOCRG-WAYWQWQTSA-N
General description
顺式-3-己烯是一种对称的顺式双取代烯烃，可由3-己烯通过硼氢化反应并继以质解反应制成。通过结合电子衍射和分子力学计算对分子结构进行气相研究，揭示了(+ac, +ac)和(-ac, +ac)形式的存在。顺式-3-己烯可与二甲基过氧化酮环氧化形成相应的环氧化物。
Application
顺式-3-己烯可通过与二异松香樟脑硼烷（Ipc2BH）进行不对称硼氢化反应而用于制备3-己醇。
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-13.0 °F - closed cup
flash_point_c
-25 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
The molecular structures of cis-3-hexene and trans-3-hexene in the gas phase by electron diffraction and molecular mechanical calculations.
Van HD, et al.
Journal of Molecular Structure, 74(1), 123-135 (1981)
Hydroboration. 61. Diisopinocampheylborane of high optical purity. Improved preparation and asymmetric hydroboration of representative cis-disubstituted alkenes.
Brown HC, et al.
The Journal of Organic Chemistry, 47(26), 5065-5069 (1982)
Hydroboration. XI. The hydroboration of acetylenes-A convenient conversion of internal acetylenes into cis-olefins and of terminal acetylenes into aldehydes
Brown HC and Zweifel G.
Journal of the American Chemical Society, 83(18), 3834-3840 (1961)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 52985-1ML | 04061832558424 |
| 52985-5ML | 04061837324345 |