531472
2-碘苯乙酸
97%
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关于此项目
线性分子式:
IC6H4CH2CO2H
化学文摘社编号:
分子量:
262.04
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
2-碘苯乙酸, 97%
InChI
1S/C8H7IO2/c9-7-4-2-1-3-6(7)5-8(10)11/h1-4H,5H2,(H,10,11)
SMILES string
OC(=O)Cc1ccccc1I
InChI key
IUHXGZHKSYYDIL-UHFFFAOYSA-N
assay
97%
mp
116-119 °C (lit.)
functional group
carboxylic acid
iodo
Quality Level
Application
2-Iodophenylacetic acid may be used in the preparation of:
- 2-iodophenylacetyl chloride
- 3,4-dimethoxyphenyl 2-iodophenylacetate
- N-{2-[2-(2-iodophenyl)-acetylamino]-ethyl}-2-(3,4- dichlorophenyl)-acetamide
General description
2-Iodophenylacetic acid is a substituted acetic acid that can be prepared from 2-iodobenzyl cyanide. It undergoes palladium-catalyzed reaction with allenes to form 1,3-butadienes. 2-Iodophenylacetic acid also undergoes photolysis in carbon tetrachloride to form the corresponding chloro compound.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Synthesis of benzo[c]chromen-6-ones via novel cyclic aryl?Pd (II)?ester enolate intermediates.
Taylor SR, et al.
Tetrahedron, 63(45), 10889-10895 (2007)
Pd?Catalyzed Reactions of Allenylphosphonates and Related Allenes with Functionalized 2?Iodophenols, 2?Iodobenzoic Acid, and 2?Iodobenzyl Alcohol Leading to Functionalized Benzofurans, Isocoumarins, and Benzopyrans.
Pavan MP, et al.
European Journal of Organic Chemistry, 5927-5940 (2009)
Regioselective Synthesis of Isoquino [1,2-b][3] benzazepines (Homoprotoberberines) through 11-Membered-Ring Stilbene Lactams Obtained by Radical Macrocyclization.
Rodriguez G, et al.
The Journal of Organic Chemistry, 64(13), 4830-4833 (1999)
Photochemical synthesis of aromatic chloro compounds from aromatic iodo compounds.
The Journal of Organic Chemistry, 35(2), 528-529 (1970)
Jonathan M Fitzsimmons et al.
Medicinal chemistry, 1(102) (2011-12-25)
Eight halogenated
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