Merck
CN
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文件

安全信息

531537

Sigma-Aldrich

1,2-环氧-2-甲基丙烷

97%

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别名:
2,2-二甲基环氧乙烷, 氧化异丁烯, 甲基环氧丙烷
经验公式（希尔记法）:
C4H8O
CAS号:
558-30-5
分子量:
72.11
EC 号:
209-193-8
MDL编号:
MFCD00066354
PubChem化学物质编号:
24877823
NACRES:
NA.23

质量水平

200

检测方案

97%

折射率

n20/D 1.374 (lit.)

bp

50-51 °C (lit.)

密度

0.812 g/mL at 25 °C (lit.)

SMILES string

CC1(C)CO1

InChI

1S/C4H8O/c1-4(2)3-5-4/h3H2,1-2H3

InChI key

GELKGHVAFRCJNA-UHFFFAOYSA-N

相关类别

警示用语：

Danger

危险分类

Carc. 2 - Flam. Liq. 2 - Muta. 2 - Skin Corr. 1C

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

-26.5 °F

闪点(°C)

-32.5 °C

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

危险化学品

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M Cornet et al.
Archives of toxicology, 65(4), 263-267 (1991-01-01)
Until now, no data are available concerning the biotransformation and toxicity of 2-methylpropene (or isobutene), a gaseous alkene widely used in industry (rubber, fuel additives, plastic polymers, adhesives, antioxidants). In this work, the biotransformation of 2-methylpropene (MP) has been studied
U Jorritsma et al.
Mutagenesis, 10(2), 101-104 (1995-03-01)
2-Methylpropene (isobutene), a gaseous compound widely used in chemical industries, is metabolized to the epoxide 2-methyl-1,2-epoxypropane. The parent compound has previously been shown to be non-mutagenic in a modified Ames test, whereas the epoxide metabolite gave a positive result. In
Paul R Carlier et al.
The Journal of organic chemistry, 71(4), 1592-1597 (2006-02-14)
Protonated epoxides feature prominently in organic chemistry as reactive intermediates. Herein, we describe 10 protonated epoxides using B3LYP, MP2, and CCSD/6-311++G calculations. Relative to CCSD, B3LYP consistently overestimates the C2-O bond length. Protonated 2-methyl-1,2-epoxypropane is the most problematic species studied
M Cornet et al.
Mutation research, 271(3), 213-221 (1992-06-01)
The mutagenic properties of 2-methylpropene (MP) and 2-methyl-1,2- epoxypropane (MEP) were investigated in the Salmonella assay. A simple exposure system, consisting of gastight tissue culture flasks, was used. This method has the advantage that the volatile test chemical is present
M Cornet et al.
Chemical research in toxicology, 8(7), 987-992 (1995-10-01)
The biotransformation of 2-methylpropene, a gaseous alkene widely used in industry, was investigated in vitro in liver tissue of rats, mice, and humans. Interspecies comparison revealed that the lowest levels of the primary epoxide metabolite were detected in incubations of
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