532851
2-碘苯甲酸甲酯
97%
别名:
邻-碘苯甲酸甲酯
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
IC6H4CO2CH3
化学文摘社编号:
分子量:
262.04
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
210-243-6
MDL number:
产品名称
2-碘苯甲酸甲酯, 97%
InChI key
BXXLTVBTDZXPTN-UHFFFAOYSA-N
InChI
1S/C8H7IO2/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5H,1H3
SMILES string
COC(=O)c1ccccc1I
assay
97%
refractive index
n20/D 1.604 (lit.)
bp
149-150 °C/10 mmHg (lit.)
density
1.784 g/mL at 25 °C (lit.)
functional group
ester
iodo
Quality Level
Application
2-碘苯甲酸甲酯可用于制备：
- N-取代的4-亚甲基-3,4-二氢-1（2H）-异喹啉-1-酮
- 甲基二苯基乙炔-2-羧酸酯
- 2-庚基苯基苯甲酸甲酯
- (E)-2- [3- [3- [2-（7-氯-2-喹啉基）乙烯基]苯基] -3-氧代丙基]苯甲酸甲酯
- 4-（2-甲氧羰基苯基）-3-（1-甲基乙氧基）环丁-3-烯-1,2-二酮
- 3-（2-甲氧基苯基）-4-甲基环丁烯-3-烯-1,2-二酮2-（乙烯缩醛）
General description
由2-碘苯甲酸经酯化反应制得2-碘苯甲酸甲酯。它与醛发生钴催化的环化反应，形成邻苯二甲酸酯衍生物。2-碘苯甲酸甲酯的微生物二羟基化形成非外消旋的碘环己烯羧酸酯中间体。该中间体形成用于制备kibdelone C的前体。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
A short synthesis of nonracemic iodocyclohexene carboxylate fragment for kibdelone and congeners.
Endoma-Arias MAA and Hudlicky T.
Tetrahedron Letters, 52(49), 6632-6634 (2011)
An efficient synthesis of LTD4 antagonist L-699,392.
The Journal of Organic Chemistry, 58(14), 3731-3735 (1993)
Palladium homogeneous and supported catalysis: synthesis of functional acetylenics and cyclisation to heterocycles.
Villemin D and Goussu D.
Heterocycles, 29(7), 1255-1261 (1989)
Highly Efficient Cyclization of o?Iodobenzoates with Aldehydes Catalyzed by Cobalt Bidentate Phosphine Complexes: A Novel Entry to Chiral Phthalides.
Chang HT, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 13(15), 4356-4363 (2007)
3-Stannylcyclobutenediones as nucleophilic cyclobutenedione equivalents. Synthesis of substituted cyclobutenediones and cyclobutenedione monoacetals and the beneficial effect of catalytic copper iodide on the Stille reaction.
Liebeskind LS and Fengl RW.
The Journal of Organic Chemistry, 55(19), 5359-5364 (1990)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持