533351
2,6-二氯苄基氯化锌 溶液
0.5 M in THF
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关于此项目
线性分子式:
Cl2C6H3CH2ZnCl
化学文摘社编号:
分子量:
260.86
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C7H5Cl2.ClH.Zn/c1-5-6(8)3-2-4-7(5)9;;/h2-4H,1H2;1H;/q;;+1/p-1
SMILES string
Cl[Zn]Cc1c(Cl)cccc1Cl
InChI key
NEPYXTRQHMZQAE-UHFFFAOYSA-M
concentration
0.5 M in THF
bp
65 °C
density
0.991 g/mL at 25 °C
functional group
chloro
storage temp.
2-8°C
Quality Level
Application
2,6-Dichlorobenzylzinc chloride can be used as a substrate in the palladium-catalyzed synthesis of 1-phenyl-2,5-hexanedione derivatives using methyl vinyl ketone and carbon monoxide.
Legal Information
Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.0 °F - closed cup
flash_point_c
-17.2 °C - closed cup
法规信息
新产品
此项目有
Pd (0)-catalyzed conjugate addition of benzylzinc chlorides to α, β-enones in an atmosphere of carbon monoxide: Preparation of 1, 4-diketones
Yuguchi M, et al.
The Journal of Organic Chemistry, 69(3), 908-914 (2004)
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