536652
(S)-(-)-2-(Boc-氨基)-1,4-丁二醇
97%
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关于此项目
线性分子式:
HOCH2CH2CH[NHCO2C(CH3)3]CH2OH
化学文摘社编号:
分子量:
205.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
MDL number:
产品名称
(S)-(-)-2-(Boc-氨基)-1,4-丁二醇, 97%
InChI
1S/C9H19NO4/c1-9(2,3)14-8(13)10-7(6-12)4-5-11/h7,11-12H,4-6H2,1-3H3,(H,10,13)/t7-/m0/s1
SMILES string
CC(C)(C)OC(=O)N[C@H](CO)CCO
InChI key
KLRRFBSWOIUAHZ-ZETCQYMHSA-N
assay
97%
optical activity
[α]20/D −8°, c = 1 in chloroform
mp
65-69 °C (lit.)
functional group
amine
hydroxyl
Quality Level
Application
(S)-(−)-2-(Boc-amino)-1,4-butanediol can be used as a reactant to synthesize:
- Thiourea-based organocatalysts for asymmetric Michael addition reactions of nitroalkenes to α-nitrocyclohexanone.
- Bis-copper (II) complex based catalysts for enantioselective Michael reactions.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Asymmetric Michael additions of α-nitrocyclohexanone to aryl nitroalkenes catalyzed by natural amino acid-derived bifunctional thioureas
Jo?rres M, et al.
Organic Letters, 14(17), 4518-4521 (2012)
Copper (II) in organic synthesis. XI. Evaluation of the ligand architecture on the efficiency of a copper (II) catalyst for enantioselective Michael reactions
Desimoni G, et al.
Tetrahedron, 51(14), 4131-4144 (1995)
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