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Merck
CN

538329

Sigma-Aldrich

N-乙酰乙酰苯胺

≥99.5%

别名:

1-(Phenylamino)-1,3-butanedione, 1-(Phenylcarbamoyl)-2-propanone, 3-Oxo-N-phenylbutanamide, 3-Oxo-N-phenylbutyramide, 4-(Phenylamino)-2,4-butanedione, Acetoacetamidobenzene

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关于此项目

线性分子式:
CH3COCH2CONHC6H5
CAS Number:
分子量:
177.20
Beilstein:
473419
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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蒸汽密度

6.1 (vs air)

质量水平

方案

≥99.5%

自燃温度

843 °F

mp

83-88 °C (lit.)

官能团

amide
ketone

SMILES字符串

CC(=O)CC(=O)Nc1ccccc1

InChI

1S/C10H11NO2/c1-8(12)7-10(13)11-9-5-3-2-4-6-9/h2-6H,7H2,1H3,(H,11,13)

InChI key

DYRDKSSFIWVSNM-UHFFFAOYSA-N

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一般描述

Acetoacetanilide (N-phenyl-3-oxobutanamide) undergoes condensation reaction with o-phenylenediamine to afford a Schiff base. Dielectric constant of acetoacetanilide crystals were found to increase on exposure to 120MeV Ag13+ ions due to increase in number of defects. Acetoacetanilide/Ce4+ system serves as an initiator during the polymerization of vinyl monomers.

应用

Acetoacetanilide may be used to synthesize:
  • azo pigments
  • acetoacetanilido-4-aminoantipyrine (Schiff base)
  • 6-aryl-2-methyl-4-oxo-N,N′-diphenyl-2-cyclohexene-1,3-dicarboxamides
  • photoluminescent lanthanide complexes

储存分类代码

11 - Combustible Solids

WGK

WGK 3

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Effect of swift heavy ion (SHI) irradiation on dielectric properties of acetoacetanilide crystals
Prabhu SG, et al.
Nuclear Instruments & Methods in Physics Research. Section B, Beam Interactions With Materials and Atoms null
Synthesis and characterisation of Cu (II), Ni (II), Mn (II), Zn (II) and VO (II) Schiff base complexes derived fromo-phenylenediamine and acetoacetanilide
Raman N, et al.
Journal of Chemical Sciences (Bangalore), 113.3 , 183-189 (2001)
Synthesis and photoluminescent properties of lanthanides acetoacetanilide complexes
Souza, E. R., et al.
Journal of Fluorescence, 23.5, 939-946 (2013)
Crystal structures of azo pigments derived from acetoacetanilide
Whitaker, A.
Journal of the Society of Dyers and Colourists, 104.7-8 , 294-300 (1988)
Syntheses of 1,3-imidazolin-2-ones and 1,3-imidazolin-2-thiones from new building blocks, gamma-aminoacetoacetanilides.
Jong Tak Lee et al.
Journal of combinatorial chemistry, 10(6), 803-806 (2008-09-27)

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