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Merck
CN

538329

N-乙酰乙酰苯胺

≥99.5%

别名:

1-(Phenylamino)-1,3-butanedione, 1-(Phenylcarbamoyl)-2-propanone, 3-Oxo-N-phenylbutanamide, 3-Oxo-N-phenylbutyramide, 4-(Phenylamino)-2,4-butanedione, Acetoacetamidobenzene

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关于此项目

线性分子式:
CH3COCH2CONHC6H5
化学文摘社编号:
102-01-2
分子量:
177.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24878321
EC Number:
202-996-4
Beilstein/REAXYS Number:
473419
MDL number:
MFCD00008780
Assay:
≥99.5%

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InChI key

DYRDKSSFIWVSNM-UHFFFAOYSA-N

InChI

1S/C10H11NO2/c1-8(12)7-10(13)11-9-5-3-2-4-6-9/h2-6H,7H2,1H3,(H,11,13)

SMILES string

CC(=O)CC(=O)Nc1ccccc1

vapor density

6.1 (vs air)

assay

≥99.5%

autoignition temp.

843 °F

mp

83-88 °C (lit.)

functional group

amide, ketone

Quality Level

100

相关类别

General description

Acetoacetanilide (N-phenyl-3-oxobutanamide) undergoes condensation reaction with o-phenylenediamine to afford a Schiff base. Dielectric constant of acetoacetanilide crystals were found to increase on exposure to 120MeV Ag13+ ions due to increase in number of defects. Acetoacetanilide/Ce4+ system serves as an initiator during the polymerization of vinyl monomers.

Application

Acetoacetanilide may be used to synthesize:
  • azo pigments
  • acetoacetanilido-4-aminoantipyrine (Schiff base)
  • 6-aryl-2-methyl-4-oxo-N,N′-diphenyl-2-cyclohexene-1,3-dicarboxamides
  • photoluminescent lanthanide complexes

存储类别

11 - Combustible Solids

wgk

WGK 3

法规信息

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分析证书(COA)

Lot/Batch Number
MKCN2031
MKCM7115
MKCL5325
MKCH4921
MKCG4054

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Synthesis and photoluminescent properties of lanthanides acetoacetanilide complexes
Souza, E. R., et al.
Journal of Fluorescence, 23.5, 939-946 (2013)
Crystal structures of azo pigments derived from acetoacetanilide
Whitaker, A.
Journal of the Society of Dyers and Colourists, 104.7-8 , 294-300 (1988)
Effect of swift heavy ion (SHI) irradiation on dielectric properties of acetoacetanilide crystals
Prabhu SG, et al.
Nuclear Instruments & Methods in Physics Research. Section B, Beam Interactions With Materials and Atoms null
Synthesis and characterisation of Cu (II), Ni (II), Mn (II), Zn (II) and VO (II) Schiff base complexes derived fromo-phenylenediamine and acetoacetanilide
Raman N, et al.
Journal of Chemical Sciences (Bangalore), 113.3 , 183-189 (2001)
On the kinetics and initiation mechanism of acrylamide polymerization using the ceric ion/acetoacetanilide system as initiator
Dong JH, et al.
Macromolecular Chemistry and Physics, 195.3, 823-831 (1994)
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