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Merck
CN

538329

N-乙酰乙酰苯胺

≥99.5%

别名:

1-(Phenylamino)-1,3-butanedione, 1-(Phenylcarbamoyl)-2-propanone, 3-Oxo-N-phenylbutanamide, 3-Oxo-N-phenylbutyramide, 4-(Phenylamino)-2,4-butanedione, Acetoacetamidobenzene

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关于此项目

线性分子式:
CH3COCH2CONHC6H5
化学文摘社编号:
102-01-2
分子量:
177.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24878321
EC Number:
202-996-4
Beilstein/REAXYS Number:
473419
MDL number:
MFCD00008780
Assay:
≥99.5%

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InChI key

DYRDKSSFIWVSNM-UHFFFAOYSA-N

InChI

1S/C10H11NO2/c1-8(12)7-10(13)11-9-5-3-2-4-6-9/h2-6H,7H2,1H3,(H,11,13)

SMILES string

CC(=O)CC(=O)Nc1ccccc1

vapor density

6.1 (vs air)

assay

≥99.5%

autoignition temp.

843 °F

mp

83-88 °C (lit.)

functional group

amide, ketone

Quality Level

100

相关类别

General description

Acetoacetanilide (N-phenyl-3-oxobutanamide) undergoes condensation reaction with o-phenylenediamine to afford a Schiff base. Dielectric constant of acetoacetanilide crystals were found to increase on exposure to 120MeV Ag13+ ions due to increase in number of defects. Acetoacetanilide/Ce4+ system serves as an initiator during the polymerization of vinyl monomers.

Application

Acetoacetanilide may be used to synthesize:
  • azo pigments
  • acetoacetanilido-4-aminoantipyrine (Schiff base)
  • 6-aryl-2-methyl-4-oxo-N,N′-diphenyl-2-cyclohexene-1,3-dicarboxamides
  • photoluminescent lanthanide complexes

存储类别

11 - Combustible Solids

wgk

WGK 3

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCN2031
MKCM7115
MKCL5325
MKCH4921
MKCG4054

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Synthesis and photoluminescent properties of lanthanides acetoacetanilide complexes
Souza, E. R., et al.
Journal of Fluorescence, 23.5, 939-946 (2013)
Crystal structures of azo pigments derived from acetoacetanilide
Whitaker, A.
Journal of the Society of Dyers and Colourists, 104.7-8 , 294-300 (1988)
Synthesis and characterisation of Cu (II), Ni (II), Mn (II), Zn (II) and VO (II) Schiff base complexes derived fromo-phenylenediamine and acetoacetanilide
Raman N, et al.
Journal of Chemical Sciences (Bangalore), 113.3 , 183-189 (2001)
Effect of swift heavy ion (SHI) irradiation on dielectric properties of acetoacetanilide crystals
Prabhu SG, et al.
Nuclear Instruments & Methods in Physics Research. Section B, Beam Interactions With Materials and Atoms null
Synthesis, spectral, redox and antimicrobial activities of Schiff base complexes derived from 1-phenyl-2, 3-dimethyl-4-aminopyrazol-5-one and acetoacetanilide
Raman N, et al.
Transition Metal Chemistry, 26.1-2, 131-135 (2001)
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