产品名称
2-三氟甲基-2-丙醇, 96%
InChI key
OCGWWLDZAFOHGD-UHFFFAOYSA-N
InChI
1S/C4H7F3O/c1-3(2,8)4(5,6)7/h8H,1-2H3
SMILES string
CC(C)(O)C(F)(F)F
assay
96%
refractive index
n20/D 1.3335 (lit.)
bp
83 °C (lit.)
density
1.17 g/mL at 25 °C (lit.)
functional group
fluoro
hydroxyl
Quality Level
Application
2-三氟甲基-2-丙醇可用作制备[18F]氟胸苷的溶剂。它也可以在硝酸/三氟乙酸酐中通过硝化反应合成 [2-（三氟甲基）-2-丙基硝酸酯]。
General description
2-三氟甲基-2-丙醇是一种氟化脂族醇。它可以由甲基锂、三氟丙酮和三氟乙烯基溴在醚中反应而制备。也它可以由甲基溴化镁和 1,1,1-三氟丙酮在乙醚中的反应合成。
Comparison of synthesis yields of 3'-deoxy-3'-[18F] fluorothymidine by nucleophilic fluorination in various alcohol solvents
Lee SJ, et al.
Journal of Labelled Compounds & Radiopharmaceuticals, 51.1, 80-82 (2008)
Nonacidic nitration of secondary amines
Bottaro JC, et al.
The Journal of Organic Chemistry, 52.11 , 2292-2294 (1987)
The Preparation and Some Reactions of Trifluorovinyllithium1
Tarrant P, et al.
The Journal of Organic Chemistry, 28.3, 839-843 (1963)
Mechanistic studies on gas-phase negative ion unimolecular decompositions. Alkoxide anions
Tumas W, et al.
Journal of the American Chemical Society, 110.9 , 2714-2722 (1988)
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