Merck
CN

540188

Sigma-Aldrich

甲基-1-羟基-2-萘甲酸盐

98%

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线性分子式:
HOC10H6CO2CH3
CAS号:
分子量:
202.21
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

mp

76-80 °C (lit.)

SMILES string

COC(=O)c1ccc2ccccc2c1O

InChI

1S/C12H10O3/c1-15-12(14)10-7-6-8-4-2-3-5-9(8)11(10)13/h2-7,13H,1H3

InChI key

HMIBDRSTVGFJPB-UHFFFAOYSA-N

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此商品
109630167045469157
1-Hydroxy-2-naphthoic acid ≥97.0%

Sigma-Aldrich

109630

1-羟基-2-萘甲酸

Methyl 3-hydroxy-2-naphthoate 97%

Sigma-Aldrich

167045

3-羟基-2-萘甲酸甲酯

6-Hydroxy-2-naphthoic acid 98%

Sigma-Aldrich

469157

6-羟基-2-萘甲酸

mp

76-80 °C (lit.)

mp

195-200 °C (dec.) (lit.)

mp

73-75 °C (lit.)

mp

240-250 °C (lit.)

一般描述

The asymmetric unit of the crystal of methyl 1-hydroxy-2-naphthoate contains two independent planar molecules that exhibit intra­molecular hydrogen bonds. Methyl 1-hydroxy-2-naphthoate can be prepared from 1-hydroxy-2-naphthoic acid, via esterification.

应用

Methyl 1-hydroxy-2-naphthoate may be used as a starting reagent for the synthesis of axially chiral benzimidazole derivatives.
It may also be employed in the synthesis of the following aza-mollugin derivatives:
  • azamollugin
  • 2-desmethyl-azamollugin
  • 2,2-didesmethyl-azamollugin

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Hitomi Nishino et al.
Bioorganic & medicinal chemistry letters, 26(2), 524-525 (2015-12-19)
Oxomollugin (2) is a degradation product of mollugin (1) and a potent inhibitor of NO-production including nuclear factor kappa B signals. In our endeavor to develop a potent anti-inflammatory compound, we synthesized several aza-derivatives of oxomollugin (2) and evaluated their
Effects of electronic structures on the excited-state intramolecular proton transfer of 1-hydroxy-2-acetonaphthone and related compounds.
Tobita S, et al.
The Journal of Physical Chemistry A, 102(27), 5206-5214 (1998)
Methyl 1-hydroxy-2-naphthoate.
Jin LF and Xiao FP.
Acta Crystallographica Section E, Structure Reports Online, 61(5), o1520-o1522 (2005)
Feijun Wang et al.
Beilstein journal of organic chemistry, 8, 726-731 (2012-09-28)
Axially chiral oxazoline-carbene ligands with an N-naphthyl framework were successfully prepared, and their coordination behavior with AuCl·SMe(2) was also investigated, affording the corresponding Au(I) complexes in moderate to high yields.

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