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Merck
CN

541281

甲亚硒酸

95%

别名:

Methylseleninic acid

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关于此项目

线性分子式:
CH3SeO2H
化学文摘社编号:
分子量:
127.00
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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产品名称

甲亚硒酸, 95%

InChI

1S/CH4O2Se/c1-4(2)3/h1H3,(H,2,3)

SMILES string

C[Se](O)=O

InChI key

UEQANLFPOFICBH-UHFFFAOYSA-N

assay

95%

mp

128-132 °C (lit.)

Quality Level

Application

甲亚硒酸可用作制备镧系元素配合物的配体。它也可用于通过与双(对甲氧基苯基)二氯化碲反应合成12元大环[(p-MeO-C6H4)2Te(μ-O)-(μ-MeSeO2)(μ4-Cl)]2

General description

甲亚硒酸是一种在有机合成中有用的氧化剂。它是在γ-谷氨酰硒-甲基硒代半胱氨酸和硒-甲基硒代半胱氨酸氧化过程中形成的主要产物。

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

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Haitao Zhang et al.
The Prostate, 70(12), 1265-1273 (2010-07-14)
Previous studies have demonstrated that physiological concentrations of methylseleninic acid (MSA) inhibits the growth of prostate cancer cells. The growth inhibitory effect could be attributed to cell cycle block and apoptosis induction. The current study was designed to investigate the
Novel europium and gadolinium complexes with methaneseleninate as ligand: Synthesis, characterization and spectroscopic study.
Souza AP, et al.
Inorganic Chemistry Communications, 15, 97-101 (2012)
Shutao Yin et al.
Apoptosis : an international journal on programmed cell death, 17(4), 388-399 (2011-12-20)
ABT-737, a novel small molecule inhibitor of Bcl-2 family proteins, holds great promise to complement current cancer therapies. However many types of solid cancer cells are resistant to ABT-737. One practical approach to improve its therapeutic efficacy is to combine
M Kotrebai et al.
Journal of chromatography. A, 866(1), 51-63 (2000-02-19)
Increasing speciation demands in clinical chemistry, toxicology and nutrition have made the determination of the total elements in a sample inadequate; the amount of an element and the chemical forms in which it is present need to be known. Inductively
Maher S Saifo et al.
Molecular cancer, 9, 310-310 (2010-12-04)
Beta-catenin is a multifunctional oncogenic protein that contributes fundamentally to cell development and biology. Elevation in expression and activity of β-catenin has been implicated in many cancers and associated with poor prognosis. Beta-catenin is degraded in the cytoplasm by glycogen

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