方案
96%
mp
56-61 °C (lit.)
官能团
chloro
SMILES字符串
Nc1cc(Cl)ccc1S
InChI
1S/C6H6ClNS/c7-4-1-2-6(9)5(8)3-4/h1-3,9H,8H2
InChI key
NGIRMPARLVGMPX-UHFFFAOYSA-N
一般描述
2-Amino-4-chlorobenzenethiol reacts with aromatic aldehydes and cyclohexanecarboxaldehyde to afford the corresponding thiazole and thiazoline derivatives. It undergoes oxidation in the presence of 1-n-butyl-3-methylimidazolium methylselenite, [bmim][SeO2(OCH3)] to form the corresponding symmetrical disulfide.
应用
2-Amino-4-chlorobenzenethiol may be used in the synthesis of:
- 2,3-dihydro-1,5-benzothiazepin-4-(5H)-ones
- 8-chloro-1-azaphenothiazine
- 5-chloro-2-(4-methoxyphenyl)-2,3-dihydro-1,3,2-benzothiazaphosphole 2-sulfide
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
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