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542644

2-氟-5-甲氧基苯甲醛

Name: 2-氟-5-甲氧基苯甲醛
Brand: ALDRICH

97%

别名:

6-氟-间茴香醛

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关于此项目

线性分子式:

FC₆H₃(OCH₃)CHO

化学文摘社编号:

105728-90-3

分子量:

154.14

NACRES:

NA.22

PubChem Substance ID:

24878620

UNSPSC Code:

12352100

MDL number:

MFCD00070795

Assay:

97%

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属性

assay

97%

refractive index

n20/D 1.532 (lit.)

bp

229-230 °C (lit.)

density

1.237 g/mL at 25 °C (lit.)

functional group

aldehyde, fluoro

SMILES string

COc1ccc(F)c(C=O)c1

InChI

1S/C8H7FO2/c1-11-7-2-3-8(9)6(4-7)5-10/h2-5H,1H3

InChI key

DKIQXHIAEMGZGO-UHFFFAOYSA-N

说明

General description

2-Fluoro-5-methoxybenzaldehyde can be prepared starting from 2-amino-5-methoxytoluene.

Application

2-Fluoro-5-methoxybenzaldehyde may be used in the synthesis of:

5,10,15,20-tetrakis(2-fluoro-5-methoxyphenyl)porphyrin
aryl(2-fluoro-5-methoxyphenyl)methanones
5′-methoxy-4-nitro-2,2′,5-trifluorobenzophenone
2-(2-fluoro-5-methoxybenzylidene)-1-(5-bromo-2-morpholinopyrimidin-4-yl) hydrazine

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

226.4 °F - closed cup

flash_point_c

108 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Steric effects on atropisomerism in tetraarylporphyrins.

Crossley MJ, et al.

Journal of the American Chemical Society, 109(2), 341-348 (1987)

Xanthone natural products via N-heterocyclic carbene catalysis: total synthesis of atroviridin.

Yumiko Suzuki et al.

The Journal of organic chemistry, 76(10), 3960-3967 (2011-04-08)

The total synthesis of atroviridin has been accomplished by a linear route involving the N-heterocyclic carbene (NHC)-catalyzed aroylation of the fluorobenzene derivative, Claisen cyclization of the O-propargylated benzophenones, and intramolecular 1,4-addition of the quinone intermediates. The result provides a viable

Synthesis of new 1, 2, 4-triazole derivatives and their anticorrosion properties on mild steel in hydrochloric acid medium.

Gurudatt DM, et al.

Journal of Molecular Liquids, 211, 275-287 (2015)

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全球贸易项目编号

货号	GTIN
542644-5G-A	04061836685935
542644-1G-A	04061836692902