542644
2-氟-5-甲氧基苯甲醛
97%
别名:
6-氟-间茴香醛
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关于此项目
线性分子式:
FC6H3(OCH3)CHO
化学文摘社编号:
分子量:
154.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
2-氟-5-甲氧基苯甲醛, 97%
InChI
1S/C8H7FO2/c1-11-7-2-3-8(9)6(4-7)5-10/h2-5H,1H3
SMILES string
COc1ccc(F)c(C=O)c1
InChI key
DKIQXHIAEMGZGO-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.532 (lit.)
bp
229-230 °C (lit.)
density
1.237 g/mL at 25 °C (lit.)
functional group
aldehyde
fluoro
Application
2-Fluoro-5-methoxybenzaldehyde may be used in the synthesis of:
- 5,10,15,20-tetrakis(2-fluoro-5-methoxyphenyl)porphyrin
- aryl(2-fluoro-5-methoxyphenyl)methanones
- 5′-methoxy-4-nitro-2,2′,5-trifluorobenzophenone
- 2-(2-fluoro-5-methoxybenzylidene)-1-(5-bromo-2-morpholinopyrimidin-4-yl) hydrazine
General description
2-Fluoro-5-methoxybenzaldehyde can be prepared starting from 2-amino-5-methoxytoluene.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
226.4 °F - closed cup
flash_point_c
108 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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Yumiko Suzuki et al.
The Journal of organic chemistry, 76(10), 3960-3967 (2011-04-08)
The total synthesis of atroviridin has been accomplished by a linear route involving the N-heterocyclic carbene (NHC)-catalyzed aroylation of the fluorobenzene derivative, Claisen cyclization of the O-propargylated benzophenones, and intramolecular 1,4-addition of the quinone intermediates. The result provides a viable
Steric effects on atropisomerism in tetraarylporphyrins.
Crossley MJ, et al.
Journal of the American Chemical Society, 109(2), 341-348 (1987)
A new synthesis of benzo [b] thiophenes utilizing an interrupted Pummerer reaction.
Kobayashi K, et al.
Tetrahedron, 65(12), 2430-2435 (2009)
Synthesis of new 1, 2, 4-triazole derivatives and their anticorrosion properties on mild steel in hydrochloric acid medium.
Gurudatt DM, et al.
Journal of Molecular Liquids, 211, 275-287 (2015)
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