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Merck
CN

542865

8-喹啉硼酸

technical grade

别名:

喹啉-8-硼酸

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关于此项目

经验公式(希尔记法):
C9H8BNO2
化学文摘社编号:
分子量:
172.98
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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产品名称

8-喹啉硼酸, technical grade

InChI

1S/C9H8BNO2/c12-10(13)8-5-1-3-7-4-2-6-11-9(7)8/h1-6,12-13H

SMILES string

OB(O)c1cccc2cccnc12

InChI key

KXJJSKYICDAICD-UHFFFAOYSA-N

grade

technical grade

form

solid

mp

>300 °C (lit.)

Quality Level

Other Notes

含不定量的酸酐

Application

Reactant involved in:
  • C-H and C-S bond activations
  • Synthesis of pyridazine via sequential amination / Suzuki coupling / alkylation reactions
  • Suzuki-Miyaura coupling reactions for synthesis of biaryl monophosphorus ligands, fused tricyclic oxa-quinolones, or substituted β-amino acids
  • Copper-catalyzed azidation with sodium azide
  • Studies of the affect of fluoride on the stability of boronic acids during click reactions

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Mayoorini Majuran et al.
ChemPlusChem, 85(2), 346-352 (2020-02-07)
We report the synthesis, photophysics, electrochemistry and electrochemiluminescence (ECL) of two dqp (dqp=2,6-di(quinoline-8-yl)pyridine) based ruthenium(II) complexes, bearing either a n-butyl ester (1) or the corresponding carboxylic acid functionality (2). The complexes were prepared from [Ru(dqp)(MeCN)3 ][PF6 ]2 by reaction with

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