549339
氯甲酸(N-癸基)酯
97%
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关于此项目
线性分子式:
ClCO2(CH2)9CH3
化学文摘社编号:
分子量:
220.74
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
259-668-9
MDL number:
Assay:
97%
InChI key
AZZCHVHSWUYCQA-UHFFFAOYSA-N
InChI
1S/C11H21ClO2/c1-2-3-4-5-6-7-8-9-10-14-11(12)13/h2-10H2,1H3
SMILES string
CCCCCCCCCCOC(Cl)=O
assay
97%
refractive index
n20/D 1.438 (lit.)
bp
226-227 °C (lit.)
density
0.956 g/mL at 25 °C (lit.)
functional group
chloro
storage temp.
2-8°C
Quality Level
General description
Decyl chloroformate is an n-alkyl chloroformate derivative that can be prepared by reacting decyl alcohol with triphosgene.
Application
Decyl chloroformate may be used in the preparation of (S)-(+)-N-decoxycarbonyl-leucine, a chiral surfactant. It may also be used to synthesize decyl chloride via decarboxylation in the presence of dimethylformamide.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Carbamate chiral surfactants for capillary electrophoresis.
Ding W and Fritz JS.
Journal of Chromatography A, 831(2), 311-320 (1999)
Dimethylformamide-catalyzed decarboxylation of alkyl chloroformates. A synthesis of primary alkyl chlorides.
Richter R and Tucker B.
The Journal of Organic Chemistry, 48(15), 2625-2627 (1983)
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