550574
甲醇-OD
99 atom % D
别名:
mono-Deuteromethanol, Methyl alcohol-OD, 氘代甲醇-d
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关于此项目
线性分子式:
CH3OD
化学文摘社编号:
分子量:
33.05
UNSPSC Code:
12142201
NACRES:
NA.21
PubChem Substance ID:
EC Number:
215-933-0
Beilstein/REAXYS Number:
1730948
MDL number:
Assay:
≥99.00%
Technique(s):
NMR: suitable
Bp:
65.5 °C (lit.)
InChI key
OKKJLVBELUTLKV-VMNATFBRSA-N
InChI
1S/CH4O/c1-2/h2H,1H3/i2D
SMILES string
[2H]OC
isotopic purity
99 atom % D
assay
≥99.00%
form
liquid
expl. lim.
5.5-36.5 % (lit.)
technique(s)
NMR: suitable
impurities
≤0.0250% water
water
refractive index
n20/D 1.327 (lit.)
bp
65.5 °C (lit.)
mp
-99 °C (lit.)
density
0.813 g/mL at 25 °C (lit.)
mass shift
M+1
Quality Level
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General description
氘代甲醇是甲醇的氘代形式。在基于NMR的科研和分析中用作溶剂。
Application
甲醇-OD 可被用作氘代试剂用于：
- APPI HDX MS (大气压光电离氢/氘交换质谱）检测。
- 由1,4-丁二醇-D8 合成 1,4-丁二醇-D6(1,4-BD-D6)。
Other Notes
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
target_organs
Eyes,Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
51.8 °F - closed cup
flash_point_c
11.0 °C - closed cup
法规信息
危险化学品
美国出口管控产品
此项目有
A New Analysis of the Rotational Spectrum of CH3OD.
Anderson T, et al.
Journal of Molecular Spectroscopy, 159(2), 410-421 (1993)
Infrared intensities of liquids XXI: integrated absorption intensities of CH3OH, CH3OD, CD3OH and CD3OD and dipole moment derivatives of methanol.
Bertie JE and Zhang SL.
Journal of Molecular Structure, 413, 333-363 (1997)
Dehydration of alcohols over alumina. VIII. Ether formation from the deuterated methanols CH3OH, CD3OH, CH3OD, and CD3OD.
Knozinger H, et al.
The Journal of Physical Chemistry, 72(8), 2770-2774 (1968)
The Raman Spectra of the Methyl Alcohols, CH3OH, CH3OD, and CH2DOD.
Halford JO, et al.
J. Chem. Phys. , 5(12), 927-932 (1937)
High Resolution Fourier Transform Far Infrared Spectroscopy of CH3OD.
Mukhopadhyay I, et al.
Journal of Molecular Spectroscopy, 186(1), 15-21 (1997)
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