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Merck
CN

55083

8-羟基喹啉-2-甲醛

≥98.0% (GC)

别名:

2-甲酰-8-喹啉醇, 2-甲酰-8-羟基喹啉, 8-羟基喹啉-2-甲醛

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关于此项目

经验公式(希尔记法):
C10H7NO2
化学文摘社编号:
分子量:
173.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
127519
Assay:
≥98.0% (GC)
Form:
solid
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InChI

1S/C10H7NO2/c12-6-8-5-4-7-2-1-3-9(13)10(7)11-8/h1-6,13H

SMILES string

Oc1cccc2ccc(C=O)nc12

InChI key

SLBPIHCMXPQAIQ-UHFFFAOYSA-N

assay

≥98.0% (GC)

form

solid

mp

97-100 °C

functional group

aldehyde

Quality Level

General description

以 2-甲基喹啉-8-醇为原料,二氧化硒为氧化剂,经氧化制得 8-羟基-2-喹啉甲醛。

Application

8-羟基-2-喹啉甲醛(8-羟基喹啉-2-甲醛)可用于以下制备过程:
  • 8-羟基-2-喹啉-1-氨基芘与 1-氨基芘的席夫碱反应
  • ( E )-2-((2-(吡啶-2-基)肼基)甲基)喹啉-8-醇(与 2-肼基吡啶偶联)
  • 8-羟基喹啉-2-甲醛肟
  • 2-[(8-羟基喹啉)-2-甲基氨基乙基]-β- D -吡喃葡萄糖苷

Other Notes

合成络合剂的结构单元

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Saptarshi Ghosh et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 188, 252-257 (2017-07-21)
The present work reports detailed photophysics of a coumarin based Schiff base, namely, (E)-7-(((8-hydroxyquinolin-2-yl)methylene)amino)-4-methyl-2H-chromen-2-one (HMC) in different solvents of varying polarity exploiting steady state absorption, fluorescence and time resolved fluorescence spectroscopy. The dominant photophysical features of HMC are discussed in
S. Sugata et al.
Chemical & Pharmaceutical Bulletin, 35, 2623-2623 (1987)
Rhombus-shaped tetranuclear [Ln4] complexes [Ln= Dy (III) and Ho (III)]: synthesis, structure, and SMM behavior.
Chandrasekhar V, et al.
Inorganic Chemistry, 52(11), 6346-6353 (2013)
S-shaped decanuclear heterometallic [Ni8Ln2] complexes [Ln (iii)= Gd, Tb, Dy and Ho]: theoretical modeling of the magnetic properties of the gadolinium analogue.
Hossain S, et al.
Dalton Transactions, 43(26), 10164-10174 (2014)
Nadia Alessandra Carmo Dos Santos et al.
Dalton transactions (Cambridge, England : 2003), 46(47), 16455-16464 (2017-11-17)
Novel cobalt, nickel, and iron complexes based on the pentadentate 8-hydroxyquinoline-di(2-picolyl)amine ligand were synthesized and thoroughly characterized. X-ray structures of both the cobalt and iron complexes were also obtained, showing the tendency to adopt a pseudo-octahedral geometry by coordination of

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