553344
异丙基异腈
97%
别名:
2-Isocyanopropane, 2-Propyl isonitrile, Isopropyl isonitrile
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关于此项目
线性分子式:
(CH3)2CHNC
化学文摘社编号:
分子量:
69.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
InChI
1S/C4H7N/c1-4(2)5-3/h4H,1-2H3
SMILES string
CC(C)[N+]#[C-]
InChI key
MJZUMMKYWBNKIP-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.371 (lit.)
bp
75 °C (lit.)
density
0.733 g/mL at 25 °C (lit.)
functional group
amine, isonitrile
storage temp.
2-8°C
Quality Level
General description
Isopropyl isocyanide is an alkyl isocyanide.
Application
Isopropyl isocyanide may be used in the preparation of:
- Ugi ligand A2C11I1, which is employed in the solid-phase Ugi synthesis.
- Pentafluorophenyl (PFP) functional monomers, via Passerini reaction.
- Dinuclear copper complex [Cu2(μ-PiPr2bipy)2{μ-CNCH(CH3)2}](PF6)2 [PiPr2bipy = 6-(diisopropylphosphanyl)-2,2′-bipyridine].
- (3E)-(Imino)thiaisoindoline 1,1-dioxide derivative.
- N,N′-diisopropylcarbodiimide (DIC) analog via reaction with propan-2-amine.
- 1-t-butyl-2-isopropyldiaziridinone via reaction with 2-methyl-2-nitrosopropane
- isopropyl isocyanate via reaction with ozone
- 1-phthalimidoazetidines via [1+3]cycloaddition reaction with 1-pththalimidoaziridines
wgk
WGK 3
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
存储类别
3 - Flammable liquids
flash_point_f
69.1 °F - closed cup
flash_point_c
20.6 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
A synthetic Protein G adsorbent based on the multi-component Ugi reaction for the purification of mammalian immunoglobulins.
Qian J, et al.
Journal of Chromatography. B, Biomedical Applications, 898, 15-23 (2012)
Palladium-Catalyzed C C Coupling of Aryl Halides with Isocyanides: An Alternative Method for the Stereoselective Synthesis of (3E)-(Imino) isoindolin-1-ones and (3E)-(Imino) thiaisoindoline 1, 1-Dioxides.
Liu B, et al.
Advanced Synthesis & Catalysis, 354(11-12), 2288-2300 (2012)
Reaction of Alkyl Isocyanides with Ozone. A New Isocyanate Synthesis1
Feuer H, et al.
The Journal of Organic Chemistry, 23(8), 1107-1109 (1958)
[1+ 3] Cycloadditions of isocyanides to azomethine ylides; synthesis and properties of 1-phthalimidoazetidines
Charrier J, et al.
The Journal of Organic Chemistry, 48(4), 481-486 (1983)
Synthesis of Carbodiimides by I2/CHP-Mediated Cross-Coupling Reaction of Isocyanides with Amines under Metal-Free Conditions.
Zhu TH, et al.
Organic Letters, 17(8), 1974-1977 (2015)
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