554065
α-溴苯乙酸乙酯
97%
别名:
α-溴苯乙酸乙酯, α-溴苯基乙酸乙酯, (±)-α-溴苯乙酸乙酯, 2-溴-2-二苯基乙酸乙酯, 2-溴-2-苯基乙酸乙酯, 2-溴苯乙酸乙酯
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关于此项目
线性分子式:
C6H5CHBrCOOCH2CH3
化学文摘社编号:
分子量:
243.10
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
折射率
n20/D >1.5390 (lit.)
沸点
89-92 °C/0.9 mmHg (lit.)
密度
1.389 g/mL at 25 °C (lit.)
官能团
bromo
ester
phenyl
SMILES字符串
CCOC(=O)C(Br)c1ccccc1
InChI
1S/C10H11BrO2/c1-2-13-10(12)9(11)8-6-4-3-5-7-8/h3-7,9H,2H2,1H3
InChI key
BKTKLDMYHTUESO-UHFFFAOYSA-N
应用
α-溴苯乙酸乙酯（EBPA）可用于合成α-乙氧羰基-N,α-二苯基硝酮。
EBPA可以用作以下反应的引发剂：
EBPA可以用作以下反应的引发剂：
- 二甲基（甲基丙烯酰氧基甲基）膦酸酯的聚合反应
- 甲基丙烯酸甲酯（MMA）的聚合反应
- 三羟甲基丙烷三丙烯酸酯（TMPTA）的聚合反应
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
230.0 °F - closed cup
闪点(°C)
110 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Mingqiang Ding et al.
Macromolecular rapid communications, 36(6), 538-546 (2015-02-05)
A concept based on diffusion-regulated phase-transfer catalysis (DRPTC) in an aqueous-organic biphasic system with copper-mediated initiators for continuous activator regeneration is successfully developed for atom transfer radical polymerization (ICAR ATRP) (termed DRPTC-based ICAR ATRP here), using methyl methacrylate (MMA) as
Control of a living radical polymerization of methacrylates by light.
Brett P Fors et al.
Angewandte Chemie (International ed. in English), 51(35), 8850-8853 (2012-07-19)
Wei Jiang et al.
Journal of colloid and interface science, 521, 62-68 (2018-03-20)
Atom transfer radical polymerization (ATRP) has been considered to be an efficient strategy for constructing functional macromolecules owing to its simple operation and versatile monomers, and thus it is of great significance to develop ideal catalysts with higher activity and
Atom transfer radical polymerization of dimethyl (methacryloyloxymethyl) phosphonate.
Mukumoto K, et al.
European Polymer Journal, 56, 11-16 (2014)
"A dinuclear gold (I) complex as a novel photoredox catalyst for light-induced atom transfer radical polymerization"
Nzulu F, et al.
Polym. Chem., 6(25), 4605-4611 (2015)
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