554065
α-溴苯乙酸乙酯
97%
别名:
α-溴苯乙酸乙酯, α-溴苯基乙酸乙酯, (±)-α-溴苯乙酸乙酯, 2-溴-2-二苯基乙酸乙酯, 2-溴-2-苯基乙酸乙酯, 2-溴苯乙酸乙酯
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关于此项目
线性分子式:
C6H5CHBrCOOCH2CH3
化学文摘社编号:
分子量:
243.10
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
220-735-2
MDL number:
产品名称
α-溴苯乙酸乙酯, 97%
InChI key
BKTKLDMYHTUESO-UHFFFAOYSA-N
InChI
1S/C10H11BrO2/c1-2-13-10(12)9(11)8-6-4-3-5-7-8/h3-7,9H,2H2,1H3
SMILES string
CCOC(=O)C(Br)c1ccccc1
assay
97%
refractive index
n20/D >1.5390 (lit.)
bp
89-92 °C/0.9 mmHg (lit.)
density
1.389 g/mL at 25 °C (lit.)
functional group
bromo
ester
phenyl
Quality Level
Application
α-溴苯乙酸乙酯（EBPA）可用于合成α-乙氧羰基-N,α-二苯基硝酮。
EBPA可以用作以下反应的引发剂：
EBPA可以用作以下反应的引发剂：
- 二甲基（甲基丙烯酰氧基甲基）膦酸酯的聚合反应
- 甲基丙烯酸甲酯（MMA）的聚合反应
- 三羟甲基丙烷三丙烯酸酯（TMPTA）的聚合反应
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Fluorescence self-quenching of substituted N, a-diphenylnitrones in various solvents.
Khoee S and Memarian HR.
Journal of Photochemistry and Photobiology A: Chemistry, 177(2), 276-285 (2006)
Activators regenerated by electron transfer for atom-transfer radical polymerization of (meth)acrylates and related block copolymers.
Wojciech Jakubowski et al.
Angewandte Chemie (International ed. in English), 45(27), 4482-4486 (2006-06-14)
"A dinuclear gold (I) complex as a novel photoredox catalyst for light-induced atom transfer radical polymerization"
Nzulu F, et al.
Polym. Chem., 6(25), 4605-4611 (2015)
Mingqiang Ding et al.
Macromolecular rapid communications, 36(6), 538-546 (2015-02-05)
A concept based on diffusion-regulated phase-transfer catalysis (DRPTC) in an aqueous-organic biphasic system with copper-mediated initiators for continuous activator regeneration is successfully developed for atom transfer radical polymerization (ICAR ATRP) (termed DRPTC-based ICAR ATRP here), using methyl methacrylate (MMA) as
Atom transfer radical polymerization of dimethyl (methacryloyloxymethyl) phosphonate.
Mukumoto K, et al.
European Polymer Journal, 56, 11-16 (2014)
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