555142
1-二苯基膦基-1′-(二叔丁基膦基)二茂铁
solid
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关于此项目
经验公式（希尔记法）:
C30H36FeP2
化学文摘社编号:
分子量:
514.40
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
1-二苯基膦基-1′-(二叔丁基膦基)二茂铁,
form
solid
Quality Level
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Coupling Reactions
mp
75-79 °C (lit.)
functional group
phosphine
SMILES string
[Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.[CH]2[CH][CH][C]([CH]2)P(c3ccccc3)c4ccccc4
InChI
1S/C17H14P.C13H22P.Fe/c1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h1-14H;7-10H,1-6H3;
InChI key
GQIMIFFIUZZVMJ-UHFFFAOYSA-N
Application
- Catalyst in microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides
- Ligand for catalytic isomerization of methylbutenenitrile via nickel systems
- Ligand for ruthenium alkylidene complexes for catalysis of metathesis reactions and catalytic norbornene polymerization
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Marvin Parasram et al.
Journal of the American Chemical Society, 136(52), 17926-17929 (2014-12-17)
A palladium (Pd)-catalyzed endo-selective Heck reaction of iodomethylsilyl ethers of phenols and aliphatic alkenols has been developed. Mechanistic studies reveal that this silyl methyl Heck reaction operates via a hybrid Pd-radical process and that the silicon atom is crucial for
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 555142-1G | 04061826696835 |