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Merck
CN

555142

1-二苯基膦基-1′-(二叔丁基膦基)二茂铁

greener alternative

solid

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关于此项目

经验公式(希尔记法):
C30H36FeP2
化学文摘社编号:
分子量:
514.40
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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产品名称

1-二苯基膦基-1′-(二叔丁基膦基)二茂铁,

form

solid

Quality Segment

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Coupling Reactions

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

75-79 °C (lit.)

functional group

phosphine

greener alternative category

SMILES string

[Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.[CH]2[CH][CH][C]([CH]2)P(c3ccccc3)c4ccccc4

InChI

1S/C17H14P.C13H22P.Fe/c1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h1-14H;7-10H,1-6H3;

InChI key

GQIMIFFIUZZVMJ-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is an unsymmetric diphosphine ligand for asymmetric catalysis, combining different phosphine environments to provide enhanced selectivity in metal-catalyzed reactions. Click here for more information.

Application

  • Catalyst in microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides
  • Ligand for catalytic isomerization of methylbutenenitrile via nickel systems
  • Ligand for ruthenium alkylidene complexes for catalysis of metathesis reactions and catalytic norbornene polymerization


存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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