562246
4-(2-四氢-2H-吡喃氧代)苯基溴化镁 溶液
0.5 M in THF
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关于此项目
经验公式（希尔记法）:
C11H13BrMgO2
化学文摘社编号:
分子量:
281.43
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
产品名称
4-(2-四氢-2H-吡喃氧代)苯基溴化镁 溶液, 0.5 M in THF
InChI
1S/C11H13O2.BrH.Mg/c1-2-6-10(7-3-1)13-11-8-4-5-9-12-11;;/h2-3,6-7,11H,4-5,8-9H2;1H;/q;;+1/p-1
SMILES string
Br[Mg]c1ccc(OC2CCCCO2)cc1
InChI key
OHPUQUBYKZJOLY-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
0.5 M in THF
bp
65 °C
density
0.961 g/mL at 25 °C
storage temp.
2-8°C
Legal Information
Rieke® Metals, Inc. 的产品，®Rieke Metals, Inc. 的注册商标
Application
4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesium bromide can be used:
- In the preparation of C-2 and C-20-diaryl steroidal derivatives.
- As an intermediate in the synthesis of multiblock copolymers having fullerene backbone for possible applications in photovoltaic devices.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
<1.4 °F - closed cup
flash_point_c
< -17 °C - closed cup
法规信息
新产品
此项目有
Synthesis of donor- acceptor multiblock copolymers incorporating fullerene backbone repeat units
Hiorns RC, et al.
Macromolecules, 43(14), 6033-6044 (2010)
Design and Diastereoselective Synthesis of C-2, C-20-Diaryl Steroidal Derivatives
Rey J, et al.
European Journal of Organic Chemistry, 2012(20), 3781-3794 (2012)
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