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Merck
CN

562505

氢氧化铯 一水合物

≥99.5% trace metals basis

别名:

Cesium hydroxide hydrate

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关于此项目

经验公式(希尔记法):
HCsO · H2O
化学文摘社编号:
分子量:
167.93
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
244-344-1
MDL number:
Assay:
≥99.5% trace metals basis
Form:
powder or crystals
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产品名称

氢氧化铯 一水合物, ≥99.5% trace metals basis

InChI key

HUCVOHYBFXVBRW-UHFFFAOYSA-M

InChI

1S/Cs.H2O/h;1H2/q+1;/p-1

SMILES string

[Cs+].[O-][H].[H]O[H]

assay

≥99.5% trace metals basis

form

powder or crystals

impurities

≤5000.0 ppm Trace Metal Analysis

mp

272 °C (lit.)

density

3.68 g/mL at 25 °C (lit.)

Quality Level

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Application

Cesium hydroxide monohydrate can be used:

  • As a catalyst to prepare unsymmetrical Bis-allyl ethers via dimerization of Baylis-Hillman adducts.
  • As a dopant to fabricate vanadium oxide thin films as a hole extraction layer for perovskite solar cells.
  • As an initiator for ring opening polymerization of monosubstituted oxiranes.
  • As a promoter to synthesize secondary amines via chemoselective N-alkylation.

Features and Benefits

  • As a strong base ≥99.5% CsOH serves as an effective catalyst in organic reactions, enhancing reaction rates and selectivity without the risk of impurities affecting the outcomes.
  • ≥99.5% CsOH is used in the synthesis of various cesium compounds, ensuring that contaminants do not interfere with chemical reactions, leading to higher yields and purity of the final products.

General description

Cesium hydroxide is a strong base that can be used in organic synthesis, as a catalyst, and as an intermediate in the production of cesium compounds.

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1A

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

非剧毒-急性毒性1
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Application of cesium hydroxide monohydrate for ring opening polymerization of monosubstituted oxiranes: characterization of synthesized polyether-diols
Zbigniew Grobelny, et al.
Polymer Bull., 78, 7301-7312 (2021)
Cesium-Doped Vanadium Oxide as the Hole Extraction Layer for Efficient Perovskite Solar Cells
Xiang Yao, et al.
ACS Omega, 3, 1117-1125 (2018)
An atom-economical and environmentally benign preparation of unsymmetrical bis-allyl ethers via dimerization of Baylis-Hillman adducts catalyzed by cesium hydroxide monohydrate
Yunkui Liu, et al.},
Synlett, 2005, 2999-3001 (2005)
Cesium Hydroxide Promoted Chemoselective N-Alkylation for the Generally Efficient Synthesis of Secondary Amines
Ralph N. Salvatore, et al.
Organic Letters, 1, 1893-1896 (1999)
David Johannes Scholz et al.
Magma (New York, N.Y.), 28(6), 591-598 (2015-10-10)
(13)C metabolic MRI using hyperpolarized (13)C-bicarbonate enables preclinical detection of pH. To improve signal-to-noise ratio, experimental procedures were refined, and the influence of pH, buffer capacity, temperature, and field strength were investigated. Bicarbonate preparation was investigated. Bicarbonate was prepared and

商品

Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.

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