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经验公式(希尔记法):
HCsO · H2O
化学文摘社编号:
分子量:
167.93
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
244-344-1
MDL number:
Assay:
≥99.5% trace metals basis
Form:
powder or crystals
产品名称
氢氧化铯 一水合物, ≥99.5% trace metals basis
InChI key
HUCVOHYBFXVBRW-UHFFFAOYSA-M
InChI
1S/Cs.H2O/h;1H2/q+1;/p-1
SMILES string
[Cs+].[O-][H].[H]O[H]
assay
≥99.5% trace metals basis
form
powder or crystals
impurities
≤5000.0 ppm Trace Metal Analysis
mp
272 °C (lit.)
density
3.68 g/mL at 25 °C (lit.)
Quality Level
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Application
Cesium hydroxide monohydrate can be used:
- As a catalyst to prepare unsymmetrical Bis-allyl ethers via dimerization of Baylis-Hillman adducts.
- As a dopant to fabricate vanadium oxide thin films as a hole extraction layer for perovskite solar cells.
- As an initiator for ring opening polymerization of monosubstituted oxiranes.
- As a promoter to synthesize secondary amines via chemoselective N-alkylation.
Features and Benefits
- As a strong base ≥99.5% CsOH serves as an effective catalyst in organic reactions, enhancing reaction rates and selectivity without the risk of impurities affecting the outcomes.
- ≥99.5% CsOH is used in the synthesis of various cesium compounds, ensuring that contaminants do not interfere with chemical reactions, leading to higher yields and purity of the final products.
General description
Cesium hydroxide is a strong base that can be used in organic synthesis, as a catalyst, and as an intermediate in the production of cesium compounds.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1A
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
非剧毒-急性毒性1
此项目有
Application of cesium hydroxide monohydrate for ring opening polymerization of monosubstituted oxiranes: characterization of synthesized polyether-diols
Zbigniew Grobelny, et al.
Polymer Bull., 78, 7301-7312 (2021)
Cesium-Doped Vanadium Oxide as the Hole Extraction Layer for Efficient Perovskite Solar Cells
Xiang Yao, et al.
ACS Omega, 3, 1117-1125 (2018)
An atom-economical and environmentally benign preparation of unsymmetrical bis-allyl ethers via dimerization of Baylis-Hillman adducts catalyzed by cesium hydroxide monohydrate
Yunkui Liu, et al.},
Synlett, 2005, 2999-3001 (2005)
Cesium Hydroxide Promoted Chemoselective N-Alkylation for the Generally Efficient Synthesis of Secondary Amines
Ralph N. Salvatore, et al.
Organic Letters, 1, 1893-1896 (1999)
David Johannes Scholz et al.
Magma (New York, N.Y.), 28(6), 591-598 (2015-10-10)
(13)C metabolic MRI using hyperpolarized (13)C-bicarbonate enables preclinical detection of pH. To improve signal-to-noise ratio, experimental procedures were refined, and the influence of pH, buffer capacity, temperature, and field strength were investigated. Bicarbonate preparation was investigated. Bicarbonate was prepared and
商品
Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.
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