3-氯苯基溴化镁

Name: 3-氯苯基溴化镁
Brand: ALDRICH

0.5 M in THF

别名:

(3-Chlorophenyl)magnesium bromide, (m-Chlorophenyl)magnesium bromide, 3-chloro phenyl magnesium bromide, 3-chlorophenyl magnesium bromide, m-chlorophenyl magnesium bromide, Bromo(3-chlorophenyl)magnesium

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所有图片(1)

About This Item

经验公式（希尔记法）:

C₆H₄BrClMg

CAS Number:

36229-42-2

分子量:

215.76

MDL编号:

MFCD00672003

UNSPSC代码:

12352103

PubChem化学物质编号:

24880124

NACRES:

NA.22

反应适用性

reaction type: Grignard Reaction

质量水平

100

浓度

0.5 M in THF

沸点

65 °C (lit.)

密度

0.960 g/mL at 25 °C (lit.)

官能团

chloro

储存温度

2-8°C

SMILES字符串

Clc1cccc([Mg]Br)c1

InChI

1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6;;/h1-2,4-5H;1H;/q;;+1/p-1

InChI key

ZIYRUWPTUPFRQU-UHFFFAOYSA-M

应用

3-Chlorophenylmagnesium bromide (o-chlorophnylmagnesium bromide) is a Grignard reagent that can be used to synthesize:

2,3-Di(o-chlorophenyl)buta-1,3-dienes by reacting with 1,4-dimethoxy 2-butyne in the presence of a copper(I) salt.
2-Bromo-5-chlorothiophen-3-yl-(3-chlorophenyl)methanol by reacting with 2-bromo-5-chlorothiophene-3-carbaldehyde.
2-(3-Chlorophenyl)-1-phenyl-1H-inden-1-ol from 2- benzoylbenzonitrile as a starting a material.