563722
3-氯苯基溴化镁
0.5 M in THF
别名:
(3-Chlorophenyl)magnesium bromide, (m-Chlorophenyl)magnesium bromide, 3-chloro phenyl magnesium bromide, 3-chlorophenyl magnesium bromide, m-chlorophenyl magnesium bromide, Bromo(3-chlorophenyl)magnesium
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关于此项目
经验公式（希尔记法）:
C6H4BrClMg
化学文摘社编号:
分子量:
215.76
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6;;/h1-2,4-5H;1H;/q;;+1/p-1
SMILES string
Clc1cccc([Mg]Br)c1
InChI key
ZIYRUWPTUPFRQU-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
0.5 M in THF
bp
65 °C (lit.)
density
0.960 g/mL at 25 °C (lit.)
functional group
chloro
storage temp.
2-8°C
Quality Level
Application
3-Chlorophenylmagnesium bromide (o-chlorophnylmagnesium bromide) is a Grignard reagent that can be used to synthesize:
- 2,3-Di(o-chlorophenyl)buta-1,3-dienes by reacting with 1,4-dimethoxy 2-butyne in the presence of a copper(I) salt.
- 2-Bromo-5-chlorothiophen-3-yl-(3-chlorophenyl)methanol by reacting with 2-bromo-5-chlorothiophene-3-carbaldehyde.
- 2-(3-Chlorophenyl)-1-phenyl-1H-inden-1-ol from 2- benzoylbenzonitrile as a starting a material.
Legal Information
Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
<1.4 °F - closed cup
flash_point_c
< -17 °C - closed cup
法规信息
危险化学品
此项目有
Novel synthesis of 2, 3-diarylbuta-1, 3-dienes from 1, 4-dimethoxybutyne-2
Ishino Y, et al.
Tetrahedron Letters, 21(16), 1527-1528 (1980)
Synthesis of 3-substituted 3H-indol-3-ols by the reaction of 2-isocyanophenyl ketones with Grignard reagents
Kobayashi K, et al.
Tetrahedron, 66(40), 7961-7964 (2010)
The discovery of 4-1-[({2, 5-dimethyl-4-[4-(trifluoromethyl) benzyl]-3-thienyl}carbonyl) amino] cyclopropyl}benzoic acid (MK-2894), a potent and selective prostaglandin E2 subtype 4 receptor antagonist
Blouin M, et al.
Journal of Medicinal Chemistry, 53(5), 2227-2238 (2010)
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