567159
1,1′-双(苯基亚膦基)二茂铁
97%, solid
别名:
1,1′-(二茂铁二基)苯膦
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关于此项目
线性分子式:
C5H4PC6H5C5H4Fe
化学文摘社编号:
分子量:
292.09
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
1,1′-双(苯基亚膦基)二茂铁, 97%
SMILES string
[Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3
InChI
1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;
InChI key
HKOUDNXXOXEYNZ-UHFFFAOYSA-N
assay
97%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp
88-92 °C (lit.)
functional group
phosphine
storage temp.
2-8°C
Quality Level
Application
Reactant for:
- Preparation of macrocyclic tridentate ferrocenylphosphine ligands
- Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
- Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
- Ring-opening reactions via ring slippage
- Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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