567159
1,1′-双(苯基亚膦基)二茂铁
更环保的选择
97%, solid
别名:
1,1′-(二茂铁二基)苯膦
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关于此项目
线性分子式:
C5H4PC6H5C5H4Fe
化学文摘社编号:
分子量:
292.09
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
1,1′-双(苯基亚膦基)二茂铁, 97%
Quality Segment
assay
97%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
mp
88-92 °C (lit.)
functional group
phosphine
greener alternative category
storage temp.
2-8°C
SMILES string
[Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3
InChI
1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;
InChI key
HKOUDNXXOXEYNZ-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. Ferrocene phosphine ligands are used as catalytic components in asymmetric hydrogenation reactions, enabling efficient and selective synthesis of chiral compounds, offering a greener, potentially more sustainable option for pharmaceutical manufacturing. Click here for more information.
Application
Reactant for:
- Preparation of macrocyclic tridentate ferrocenylphosphine ligands
- Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
- Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
- Ring-opening reactions via ring slippage
- Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)