568112
二异丙基锌 溶液
1.0 M in toluene
别名:
Bis(1-methylethyl)zinc, Bis(isopropyl)zinc
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关于此项目
线性分子式:
Zn(CH(CH3)2)2
化学文摘社编号:
分子量:
151.57
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/2C3H7.Zn/c2*1-3-2;/h2*3H,1-2H3;
SMILES string
CC(C)[Zn]C(C)C
InChI key
KDUNMLRPPVCIGP-UHFFFAOYSA-N
concentration
1.0 M in toluene
density
0.895 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
Application
Diisopropylzinc is a general reagent used in the organic asymmetric synthesis such as the asymmetric synthesis of [6]?helicene, [5]-helicene and, enantiomerically enriched 5-pyrimidyl alkanol.
Packaging
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
target_organs
Central nervous system, Respiratory system
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
23.0 °F - closed cup
flash_point_c
-5 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react. 2
法规信息
危险化学品
易制毒化学品（3类）
此项目有
Highly enantioselective synthesis of organic compound using right-and left-handed helical silica.
Sato, Itaru et al.
Tetrahedron Letters, 44(4), 721-724 (2003)
Asymmetric Synthesis of Chiral Secondary Alcohols with Isopropyl Substituents by the Catalytic Enantioselective Addition of Diisopropylzinc to Aldehydes Using N, N-Dialkylnorephedrines as Chiral Catalysts.
Soai, Kenso et al.
The Journal of Organic Chemistry, 59(25), 7908-7909 (1994)
Stereoselective preparation and reactions of configurationally defined dialkylzinc compounds.
Boudier, Andreas et al.
Chemistry?A European Journal , 6(15), 2748-2761 (2000)
Asymmetric induction by helical hydrocarbons:[6]-and [5] helicenes.
Sato, Itaru et al.
Angewandte Chemie (International Edition in English), 113(6), 1130-1132 (2001)
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