57110
三氯化铟 水合物
~39% indium basis, 2-3 mol/mol water
别名:
Trichloroindium, indium trichloride
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关于此项目
线性分子式:
InCl3 · aq
化学文摘社编号:
分子量:
221.18 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
233-043-0
MDL number:
InChI key
KYCHGXYBBUEKJK-UHFFFAOYSA-K
InChI
1S/3ClH.In.H2O/h3*1H;;1H2/q;;;+3;/p-3
SMILES string
O.Cl[In](Cl)Cl
reaction suitability
core: indium, reagent type: catalyst
concentration
~39% In
impurities
2-3 mol/mol water
Application
Reagent/catalyst for various organic transformations, e.g. allylation of aldehydes, ketones, and quinones; Diels-Alder reaction; the aldol reaction; Michael additions; the reductive Friedel-Crafts;
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C - STOT RE 1 Inhalation
target_organs
Lungs
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Chapman, C. J.; Frost, C. G. et al.
Tetrahedron Letters, 42, 773-773 (2001)
S Kobayashi et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 6(19), 3491-3494 (2000-11-10)
Group 3-15 metal chlorides (Lewis acids) were classified on the basis of activity and aldehyde- and aldimine-selectivity in an addition reaction of a silyl enol ether. Based on the experimental results, metal chlorides (Lewis acids) were classified as follows: A
Loh, T.-P.; Li, X.-R.,
Angewandte Chemie (International Edition in English), 36, 980-980 (1997)
Reddy, B. G.; Kumareswaran, R. et al.
Tetrahedron Letters, 41, 10333-10333 (2000)
Sebastian Bernhardt et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(3), 828-833 (2012-12-21)
Magnesium, indium, palladium: An efficient one-pot procedure for the direct preparation of triorganoindium reagents from organic halides by means of magnesium insertion in the presence of InCl(3) and LiCl is reported (see scheme). The organoindium reagents are obtained in good
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