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Merck
CN

572365

氧化钐掺杂的氧化铈(IV)

nanopowder, contains 15 mol % samarium as dopant

别名:

SDC, 钐掺杂的二氧化铈

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关于此项目

经验公式(希尔记法):
CeO2
分子量:
172.11
UNSPSC Code:
26111700
PubChem Substance ID:
MDL number:
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InChI

1S/Ce.2O.Sm

SMILES string

[Sm].O=[Ce]=O

InChI key

AQGZISMLQKBRRO-UHFFFAOYSA-N

form

nanopowder

contains

15 mol % samarium as dopant

composition

Ce0.85Sm0.15O2

reaction suitability

reagent type: catalyst
core: cerium

particle size

<100 nm

application(s)

battery manufacturing

General description

Cerium(IV) oxide-samarium doped nanopowder (15% mol samarium doped) (SDC) is an electrolytic material with a high oxygen ion conductivity. Samarium ion acts as an aliovalent cation that can be incorporated into the host lattice to increase the oxygen vacancy concentration and improve the oxide ion conduction in cerium oxide. It can be synthesized by reverse strike co-precipitation technique.
Samarium doped ceria may be used as an electrolyte in solid oxide fuel cells (SOFCs). Electrical conductivity as a function of temperature of doped ceria was investigated in a study. Relation of dopant type, oxygen vacancy ordering and ionic conductivity was investigated by transmission electron microscopy and electron energy loss spectroscopy.

Application

Cerium(IV) oxide-samarium doped can be used in the fabrication of solid oxide fuel cells (SOFCs), which can further be used as environmentally-friendly sources of alternative energy.

Packaging

Packaged in glass bottles

存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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历史批次信息供参考:

分析证书(COA)

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Intermediate-temperature electrochemical performance of a polycrystalline PrBaCo2O5+ δ cathode on samarium-doped ceria electrolyte.
Chen D, et al.
Journal of Power Sources, 188(1), 96-105 (2009)
Stephan Immenschuh et al.
Transplantation, 99(1), 56-62 (2014-08-15)
Treatment of patients with antibody-mediated rejection (AMR) after kidney transplantation by rituximab and plasmapheresis is ambiguous. Because of its unknown efficiency and serious side effects, biomarkers, which are predictive for responsiveness to this treatment in AMR patients, are required. Twenty
Oxygen vacancy ordering in heavily rare-earth-doped ceria.
Ou DR, et al.
Applied Physics Letters, 89(17) (2006)
Diego H Sanchez et al.
PLoS genetics, 10(11), e1004806-e1004806 (2014-11-21)
Epigenetic mechanisms suppress the transcription of transposons and DNA repeats; however, this suppression can be transiently released under prolonged heat stress. Here we show that the Arabidopsis thaliana imprinted gene SDC, which is silent during vegetative growth due to DNA
Jun Zhang et al.
Scientific reports, 4, 7082-7082 (2014-11-19)
In this work, redox-active Mn or Cr is introduced to the B site of redox stable perovskite Sr(0.95)Ti(0.9)Nb(0.1)O3.00 to create oxygen vacancies in situ after reduction for high-temperature CO2 electrolysis. Combined analysis using X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron

商品

As with all types of fuel cells, a Solid Oxide Fuel Cell (SOFC) is capable of efficiently transforming chemical energy into electrical energy.

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