574066
1,3-双(2,4,6-三甲基苯基)氯化咪唑
别名:
1,3-二氢-1,3-二甲基-2H-咪唑-2-亚立德盐酸盐, 1,3-二甲基咪唑氯化物, 1,3-双（均三）咪唑氯化物
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关于此项目
经验公式（希尔记法）:
C21H25ClN2
化学文摘社编号:
分子量:
340.89
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
反应适用性
reagent type: ligand
质量水平
mp
>300 °C (lit.)
SMILES字符串
[Cl-].Cc1cc(C)c(c(C)c1)-n2cc[n+](c2)-c3c(C)cc(C)cc3C
InChI
1S/C21H25N2.ClH/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;/h7-13H,1-6H3;1H/q+1;/p-1
InChI key
OTOSIXGMLYKKOW-UHFFFAOYSA-M
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Thi Kim Hoang Trinh et al.
Physical chemistry chemical physics : PCCP, 21(31), 17036-17046 (2019-07-30)
Although N-heterocyclic carbenes (NHCs) have brought profound changes in catalytic organic synthesis, their generation generally requires an inert atmosphere and harsh conditions. To overcome these limitations, an air-stable NHC photogenerator has been developed involving two mild components: 1,3-bis(mesityl)imidazolium tetraphenylborate (IMesH+BPh4-)
Thi Kim Hoang Trinh et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(39), 9242-9252 (2019-04-26)
In the search of smarter routes to control the conditions of N-heterocyclic carbene (NHCs) formation, a two-component air-stable NHC photogenerating system is reported. It relies on the irradiation at 365 nm of a mixture of 2-isopropylthioxanthone (ITX) with 1,3-bis(mesityl)imidazoli(ni)um tetraphenylborate. The
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