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Merck
CN

578681

二氯化(3-甲基-2-丁烯亚基)二(三环己基膦)钌

别名:

Bis(tricyclohexylphosphine)isopentenylidene ruthenium dichloride, Grubbs Catalyst 1st Generation 801

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关于此项目

经验公式(希尔记法):
C41H74Cl2P2Ru
化学文摘社编号:
分子量:
800.95
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
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InChI

1S/2C18H33P.C5H8.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-4-5(2)3;;;/h2*16-18H,1-15H2;1,4H,2-3H3;2*1H;/q;;;;;+2/p-2

SMILES string

Cl[Ru]Cl.[CH][CH][C](C)C.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C4CCC(CC4)P(C5CCCCC5)C6CCCCC6

InChI key

INCDKKABOVOFIV-UHFFFAOYSA-L

reaction suitability

reagent type: catalyst
core: ruthenium

mp

160-165 °C (lit.)

storage temp.

2-8°C

Application

Kinetic application profile similar to that of Grubbs Catalyst® 1st Generation.

Legal Information

This product is subject to US patent 5,969,170 and associated foreign equivalents thereof. This product includes a limited one-time, non-exclusive, non-transferable license to use the Product for research purposes only. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the rights of others. For questions, please contact us at aldrich@sial.com
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Sol. 1

存储类别

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Grubbs, R. H.
Tetrahedron, 7117-7117 (2004)
Trnka, T. M.; Grubbs, R. H.
Accounts of Chemical Research, 18-18 (2001)
Schrodi, Y.; Pederson, R. L.
Aldrichimica Acta, 45-45 (2007)

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