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About This Item
经验公式（希尔记法）:
C4H5BrO2
CAS Number:
分子量:
164.99
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23
质量水平
方案
95%
沸点
70-75 °C/48 mmHg (lit.)
密度
1.556 g/mL at 25 °C (lit.)
储存温度
−20°C
SMILES字符串
COC(=O)C(Br)=C
InChI
1S/C4H5BrO2/c1-3(5)4(6)7-2/h1H2,2H3
InChI key
HVJXPDPGPORYKY-UHFFFAOYSA-N
应用
Methyl α-bromoacrylate can undergo radical copolymerization with vinyl triacetoxysilane (VTAS) in the presence of azobisisobutyronitrile as the initiator. Dibromocyclopropanation of methyl α-bromoacrylate can yield methyl 1,1,2-tribromocyclopropanecarboxylate. It may be reduced with zinc dust and deuterium oxide to synthesize. Methyl acrylate-α-d with a high isotopic purity. These may undergo conjugate addition with methoxide, thiolates, oxime anions, hydrazones and EtZnCl to afford ester enolates.
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
134.6 °F - closed cup
闪点(°C)
57 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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