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Merck
CN

591688

叔丁基二苯基膦

97%

别名:

NSC 244302

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关于此项目

线性分子式:
(C6H5)2PC(CH3)3
化学文摘社编号:
分子量:
242.30
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
EC Number:
227-848-6
MDL number:
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Quality Segment

assay

97%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplings

bp

144-146 °C/2 mmHg (lit.)

mp

52-57 °C (lit.)

functional group

phosphine

SMILES string

CC(C)(C)P(c1ccccc1)c2ccccc2

InChI

1S/C16H19P/c1-16(2,3)17(14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3

InChI key

QZUPHAGRBBOLTB-UHFFFAOYSA-N

Application

Catalyst for:
  • Nickel/Lewis acid-catalyzed carbocyanation of alkynes with acetonitrile or substituted acetonitriles
  • Palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions
  • Palladium to form a catalyst for methoxycarbonylation reactions
  • Ru-catalyzed transfer hydrogenation in reductive coupling of disubstituted allenes with aldehydes
  • Stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes

  • Phosphine ligand in nickel-catalyzed carbocyanation of alkynes
  • Monodentate P-Donor Ligands (LKB-P)


存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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